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Absorption spectrum of (H2O)-O-18 in the range 12 400-14 520 cm(-1)

Tanaka, M; Brault, JW; Tennyson, J; (2002) Absorption spectrum of (H2O)-O-18 in the range 12 400-14 520 cm(-1). J MOL SPECTROSC , 216 (1) 77 - 80. 10.1006/jmsp.2002.8670. Green open access

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Abstract

Fourier transform spectra recorded using (a) natural abundance water vapor, (b) (H2O)-O-18-enriched water vapor, and (c) (H2O)-O-17-enriched water vapor are analyzed. The ratio of intensities in three spectra is used to identify 927 lines due to absorption by (H2O)-O-18. Intensities and self-broadening parameters are derived for these lines. Using theoretical linelists, comparisons with previously assigned (H2O)-O-16 spectra, and automatic searches for combination differences, 747 lines are assigned. These lines belong to 14 vibrational states in the 3nu + delta and 4nu polyads. Newly determined (H2O)-O-18 vibrational band origins include 4nu(1) at 13 793.09 cm(-1), 3nu(1) + nu(3) at 13 795.40 cm(-1), 2nu(1) + 2nu(3) at 14 188.82 cm(-1), nu(1) + 3nu(3) at 14 276.34 cm(-1), and 2nu(2) + 2nu(2) + nu(3) at 13 612.71 cm(-1). These results are compared with data in HITRAN. (C) 2002 Elsevier Science (USA).

Type: Article
Title: Absorption spectrum of (H2O)-O-18 in the range 12 400-14 520 cm(-1)
Open access status: An open access version is available from UCL Discovery
DOI: 10.1006/jmsp.2002.8670
Keywords: HIGH-RESOLUTION SPECTRUM, INTERACTING VIBRATIONAL-STATES, EXPERIMENTAL ENERGY-LEVELS, WATER-VAPOR SPECTRUM, LINE POSITIONS, CM-1, INTENSITIES, DATABASE, HEXAD
UCL classification: UCL
UCL > Provost and Vice Provost Offices
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Physics and Astronomy
URI: https://discovery.ucl.ac.uk/id/eprint/1255
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