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Chemically Processed Porous V2O5 Thin-Film Cathodes for High-Performance Thin-film Zn-Ion Batteries

Luo, Jingli; Cao, Mengjue; Naresh, Nibagani; Borah, Jnanraj; Li, Shuhui; Wang, Tianlei; Sarma, Bimal K; ... Boruah, Buddha Deka; + view all (2024) Chemically Processed Porous V2O5 Thin-Film Cathodes for High-Performance Thin-film Zn-Ion Batteries. Advanced Functional Materials , Article 2417607. 10.1002/adfm.202417607. (In press). Green open access

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Abstract

Thin-film rechargeable batteries have a wide range of applications due to their unique properties such as small size, thinness, and the ability to power smart devices, including portable electronic devices, medical devices, smart cards, RFID tags, and Internet of Things (IoT) devices. Processing thin-film electrodes for these batteries generally relies on standard physical vapor deposition technologies. However, producing porous thin-films using these techniques presents significant challenges. Here, a rapid and cost-effective chemical route for processing porous vanadium oxide (V2O5) thin-film cathodes for application in Zinc-ion-based thin-film batteries (Zn-TFBs) is explored. The V2O5 precursor process uses an industrially viable spraying technique, which not only offers impressive charge storage performance of an areal capacity of 47.34 µAh cm−2, areal energy of 50.18 µWh cm−2, and areal power of 53 µW cm−2 at 50 µA cm−2 in the optimized gel-electrolyte composition. This study introduces a cost-effective and industrially viable method for processing highly porous thin-film cathodes, enabling the production of high-performance, affordable, and safer thin-film batteries.

Type: Article
Title: Chemically Processed Porous V2O5 Thin-Film Cathodes for High-Performance Thin-film Zn-Ion Batteries
Open access status: An open access version is available from UCL Discovery
DOI: 10.1002/adfm.202417607
Publisher version: http://dx.doi.org/10.1002/adfm.202417607
Language: English
Additional information: Copyright © 2024 The Author(s). Advanced Functional Materials published by Wiley-VCH GmbH This is an open access article under the terms of the Creative Commons Attribution License, https://creativecommons.org/licenses/by/4.0/, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
Keywords: Chemically process; high-performance; V2O5 thin-film; zinc-ion thin-film batteries
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > MAPS Faculty Office
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > MAPS Faculty Office > Institute for Materials Discovery
URI: https://discovery.ucl.ac.uk/id/eprint/10200689
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