Salter, Patrick S;
Villar, M Pilar;
Lloret, Fernando;
Reyes, Daniel F;
Krueger, Marta;
Henderson, Calum S;
Araujo, Daniel;
(2024)
Laser Engineering Nanocarbon Phases within Diamond for Science and Electronics.
ACS Nano
10.1021/acsnano.3c07116.
(In press).
Preview |
PDF
salter-et-al-2024-laser-engineering-nanocarbon-phases-within-diamond-for-science-and-electronics.pdf - Published Version Download (8MB) | Preview |
Abstract
Diamond, as the densest allotrope of carbon, displays a range of exemplary material properties that are attractive from a device perspective. Despite diamond displaying high carbon-carbon bond strength, ultrashort (femtosecond) pulse laser radiation can provide sufficient energy for highly localized internal breakdown of the diamond lattice. The less-dense carbon structures generated on lattice breakdown are subject to significant pressure from the surrounding diamond matrix, leading to highly unusual formation conditions. By tailoring the laser dose delivered to the diamond, it is shown that it is possible to create continuously modified internal tracks with varying electrical conduction properties. In addition to the widely reported conducting tracks, conditions leading to semiconducting and insulating written tracks have been identified. High-resolution transmission electron microscopy (HRTEM) is used to visualize the structural transformations taking place and provide insight into the different conduction regimes. The HRTEM reveals a highly diverse range of nanocarbon structures are generated by the laser irradiation, including many signatures for different so-called diaphite complexes, which have been seen in meteorite samples and seem to mediate the laser-induced breakdown of the diamond. This work offers insight into possible formation methods for the diamond and related nanocarbon phases found in meteorites.
| Type: | Article |
|---|---|
| Title: | Laser Engineering Nanocarbon Phases within Diamond for Science and Electronics |
| Location: | United States |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1021/acsnano.3c07116 |
| Publisher version: | https://doi.org/10.1021/acsnano.3c07116 |
| Language: | English |
| Additional information: | © 2024 The Authors. Published by American Chemical Society. This publication is licensed under CC-BY 4.0 (https://creativecommons.org/licenses/by/4.0/). |
| Keywords: | diamond, electronic devices, graphitic wires, laser processing, meteorites |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Electronic and Electrical Eng |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10186135 |
Archive Staff Only
 |
View Item |
