Dos Santos, Naiara de Oliveira;
Busquets, Rosa;
Campos, Luiza C;
(2023)
Insights into the removal of microplastics and microfibres by Advanced Oxidation Processes.
Science of The Total Environment
, 861
, Article 160665. 10.1016/j.scitotenv.2022.160665.
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Abstract
Water treatment plants' effluents are hotspots of microplastics (MPs) and microfibres (MFs) released into the aquatic environment because they were not designed to capture these particles. Special attention should be given to MFs, since they mainly come from laundry and are related to one of the main MP shapes detected in water and wastewater treatment plants. In this sense, Advanced Oxidation Processes (AOPs) could be a feasible solution for tackling MP and MF pollution, however, it is still premature to extract conclusions due to the limited number of studies on the degradation of these particles (specifically MFs) using AOPs. This review addresses the impacts of AOPs on MPs/MFs, focusing on their degradation efficiency, toxicity, and sustainability of the processes, among other aspects. The review points out that polyamide MFs can achieve mass loss >90% by photocatalytic system using TiO2. Also, the low oxidation of MPs (<30 %) by conventional Fenton process affects mainly the surface of the MPs. However, other Fenton-based processes can provide better removal of some types of MPs, mainly using temperatures >100 °C, reaction time ≥ 5 h, and initial pH ≤ 3, achieving MP weight loss up to 96 %. Despite these results, better operating conditions are still required for AOPs since the ones reported so far are not feasible for full-scale application. Additionally, ozonation in treatment plants has increased the fragmentation of MPs (including MFs), leading to a new generation of MPs. More attention is needed on toxicity effects of intermediates and methods of analysis employed for the analysis of MPs/MFs in wastewater effluent should be standardized so that studies can be compared effectively. Future research should focus on the sustainability of the AOP for MP removal in water treatment (power consumption, chemicals consumed and operational costs) for a better understanding of full-scale applicability of AOP adapted to MP treatment.
| Type: | Article |
|---|---|
| Title: | Insights into the removal of microplastics and microfibres by Advanced Oxidation Processes |
| Location: | Netherlands |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1016/j.scitotenv.2022.160665 |
| Publisher version: | https://doi.org/10.1016/j.scitotenv.2022.160665 |
| Language: | English |
| Additional information: | This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third-party material in this article are included in the Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ |
| Keywords: | Electro-Fenton, H(2)O(2), Ozone, Photo-Fenton, Photocatalysis, Thermal-Fenton |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Civil, Environ and Geomatic Eng |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10161812 |
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