Haynes, Cally JE;
von Krbek, Larissa KS;
(2022)
Hopping protons in supramolecular catalysis.
Nature Chemistry
, 14
(9)
pp. 969-971.
10.1038/s41557-022-01024-w.
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Abstract
Supramolecular catalysis can emulate many features of enzymatic transformations. Now, a complex proton wire mechanism — enabling the dual activation of a nucleophile and an electrophile through reciprocal proton transfer — has been shown to operate during the β-glycosylation of sugars within a self-assembled capsule.
| Type: | Article |
|---|---|
| Title: | Hopping protons in supramolecular catalysis |
| Location: | England |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1038/s41557-022-01024-w |
| Publisher version: | https://doi.org/10.1038/s41557-022-01024-w |
| Language: | English |
| Additional information: | This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions. |
| Keywords: | Catalysis, Models, Molecular, Protons |
| UCL classification: | UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry UCL > Provost and Vice Provost Offices > UCL BEAMS UCL |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10156904 |
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