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Tertiary Alkylative Suzuki-Miyaura couplings

Nishikata, T; Sheppard, T; Tsuchiya, N; (2022) Tertiary Alkylative Suzuki-Miyaura couplings. Synthesis 10.1055/a-1732-4597. (In press).

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Abstract

The Suzuki-Miyaura coupling is extremely useful to construct Csp2-Csp2 carbon bonds. On the other hand, Csp2-Csp3 coupling reactions are do not work well, and tert-alkylative Suzuki-Miyaura coupling is particularly challenging due to problematic oxidative addition and beta-hydride elimination side reactions. In this short review, we will introduce recent examples of tert-alkylative Suzuki-Miyaura couplings with tert-alkyl electrophiles or -boron reagents. The review will mainly focus on catalyst and product structures and the proposed mechanisms .

Type: Article
Title: Tertiary Alkylative Suzuki-Miyaura couplings
DOI: 10.1055/a-1732-4597
Publisher version: https://doi.org/10.1055/a-1732-4597
Language: English
Additional information: This version is the author accepted manuscript. For information on re-use, please refer to the publisher's terms and conditions.
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry
URI: https://discovery.ucl.ac.uk/id/eprint/10141680
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