Nishikata, T;
Sheppard, T;
Tsuchiya, N;
(2022)
Tertiary Alkylative Suzuki-Miyaura couplings.
Synthesis
, 54
(10)
pp. 2340-2349.
10.1055/a-1732-4597.
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Abstract
The Suzuki-Miyaura coupling is extremely useful to construct Csp2-Csp2 carbon bonds. On the other hand, Csp2-Csp3 coupling reactions are do not work well, and tert-alkylative Suzuki-Miyaura coupling is particularly challenging due to problematic oxidative addition and beta-hydride elimination side reactions. In this short review, we will introduce recent examples of tert-alkylative Suzuki-Miyaura couplings with tert-alkyl electrophiles or -boron reagents. The review will mainly focus on catalyst and product structures and the proposed mechanisms.
| Type: | Article |
|---|---|
| Title: | Tertiary Alkylative Suzuki-Miyaura couplings |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1055/a-1732-4597 |
| Publisher version: | https://doi.org/10.1055/a-1732-4597 |
| Language: | English |
| Additional information: | This version is the author accepted manuscript. For information on re-use, please refer to the publisher's terms and conditions. |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10141680 |
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