UCL Discovery
UCL home » Library Services » Electronic resources » UCL Discovery

Tertiary Alkylative Suzuki-Miyaura couplings

Nishikata, T; Sheppard, T; Tsuchiya, N; (2022) Tertiary Alkylative Suzuki-Miyaura couplings. Synthesis , 54 (10) pp. 2340-2349. 10.1055/a-1732-4597. Green open access

[thumbnail of a-1732-4597.pdf]
a-1732-4597.pdf - Accepted Version

Download (1MB) | Preview


The Suzuki-Miyaura coupling is extremely useful to construct Csp2-Csp2 carbon bonds. On the other hand, Csp2-Csp3 coupling reactions are do not work well, and tert-alkylative Suzuki-Miyaura coupling is particularly challenging due to problematic oxidative addition and beta-hydride elimination side reactions. In this short review, we will introduce recent examples of tert-alkylative Suzuki-Miyaura couplings with tert-alkyl electrophiles or -boron reagents. The review will mainly focus on catalyst and product structures and the proposed mechanisms.

Type: Article
Title: Tertiary Alkylative Suzuki-Miyaura couplings
Open access status: An open access version is available from UCL Discovery
DOI: 10.1055/a-1732-4597
Publisher version: https://doi.org/10.1055/a-1732-4597
Language: English
Additional information: This version is the author accepted manuscript. For information on re-use, please refer to the publisher's terms and conditions.
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry
URI: https://discovery.ucl.ac.uk/id/eprint/10141680
Downloads since deposit
Download activity - last month
Download activity - last 12 months
Downloads by country - last 12 months

Archive Staff Only

View Item View Item