Li, J;
Li, F;
Yang, Q;
Wang, S;
Sun, H;
Yang, Q;
Tang, J;
(2021)
Tailoring collaborative N–O functionalities of graphene oxide for enhanced selective oxidation of benzyl alcohol.
Carbon
, 182
pp. 715-724.
10.1016/j.carbon.2021.06.062.
Preview |
Text
Manuscript.pdf - Accepted Version Download (1MB) | Preview |
Abstract
Benzaldehyde (BzH) is an important chemical for industrial feedstock. However, the conventional production processes heavily rely on precious metal catalysts and bring about unavoidable pollution issues. Here we report a new catalytic process to use N-doped graphene oxide (NGO) as the catalyst for oxidation of benzyl alcohol (BzOH) into BzH by an environmentally benign oxidant, peroxymonosulfate (PMS). Different approaches are developed to synthesize carbonylated NGO, which shows higher catalytic efficiency than Cdouble bondO-deficient NGO. The optimized catalyst could achieve 96% BzOH conversion and unprecedented 82% BzH yield under mild temperature (50 °C), superior to some precious metal catalysts reported. Experimental studies unveil the indispensable roles of pyridinic N and ketonic Cdouble bondO groups in forming an electron bridge between BzOH and PMS for non-radical oxidation, or separately inducing radical oxidation. The non-radical oxidation process is more selective in yielding BzH. Furthermore, the yielded BzH is free from over-oxidation into benzoic acid under various reaction conditions, because the radicals preferentially react with BzOH other than BzH and the BzH can hardly adsorb on graphene sheets, thus inhibiting its further oxidation. This work provides a cheap material and mechanic understanding of carbocatalysis for green organic synthesis with environmental and economic perspectives.
| Type: | Article |
|---|---|
| Title: | Tailoring collaborative N–O functionalities of graphene oxide for enhanced selective oxidation of benzyl alcohol |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1016/j.carbon.2021.06.062 |
| Publisher version: | https://doi.org/10.1016/j.carbon.2021.06.062 |
| Language: | English |
| Additional information: | This version is the author accepted manuscript. For information on re-use, please refer to the publisher's terms and conditions. |
| Keywords: | N-doped graphene, Benzaldehyde, Selective oxidation, Dual active sites, Electron transfer |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Chemical Engineering |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10136166 |
Archive Staff Only
 |
View Item |
