Nicholson, W;
Howard, JL;
Magri, G;
Seastram, AC;
Khan, A;
Bolt, RRA;
Morrill, LC;
... Browne, DL; + view all
(2021)
Ball-Milling-Enabled Reactivity of Manganese Metal**.
Angewandte Chemie International Edition
10.1002/anie.202108752.
(In press).
Preview |
Text
anie.202108752.pdf - Published Version Download (1MB) | Preview |
Abstract
Efforts to generate organomanganese reagents under ball-milling conditions have led to the serendipitous discovery that manganese metal can mediate the reductive dimerization of arylidene malonates. The newly uncovered process has been optimized and its mechanism explored using CV measurements, radical trapping experiments, EPR spectroscopy, and solution control reactions. This unique reactivity can also be translated to solution whereupon pre-milling of the manganese is required.
| Type: | Article |
|---|---|
| Title: | Ball-Milling-Enabled Reactivity of Manganese Metal** |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1002/anie.202108752 |
| Publisher version: | https://doi.org/10.1002/anie.202108752 |
| Language: | English |
| Additional information: | © 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/). |
| Keywords: | ball milling, electron paramagnetic spectroscopy, manganese, organometallics, reductive coupling |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > School of Life and Medical Sciences UCL > Provost and Vice Provost Offices > School of Life and Medical Sciences > Faculty of Life Sciences UCL > Provost and Vice Provost Offices > School of Life and Medical Sciences > Faculty of Life Sciences > UCL School of Pharmacy UCL > Provost and Vice Provost Offices > School of Life and Medical Sciences > Faculty of Life Sciences > UCL School of Pharmacy > Pharma and Bio Chemistry |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10134780 |
Archive Staff Only
 |
View Item |
