Cherkasov, N;
Murzin, DY;
Catlow, CRA;
Chutia, A;
(2021)
Selectivity of the Lindlar catalyst in alkyne semi-hydrogenation: a direct liquid-phase adsorption study.
Catalysis Science & Technology
10.1039/d1cy01016f.
(In press).
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Abstract
We study the alkyne semi-hydrogenation selectivity over Pd and Lindlar catalyst with liquid phase adsorption. The results indicate that there are strongly-adsorbing alkyne and alkene sites; alkenes react non-selectively over the alkene adsorption sites. DFT studies indicate that the non-selective sites are low-coordination Pd atoms in the nanoparticles.
| Type: | Article |
|---|---|
| Title: | Selectivity of the Lindlar catalyst in alkyne semi-hydrogenation: a direct liquid-phase adsorption study |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1039/d1cy01016f |
| Publisher version: | https://doi.org/10.1039/d1cy01016f |
| Language: | English |
| Additional information: | This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10133369 |
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