Giannakoudakis, DA;
Qayyum, A;
Lomot, D;
Besenhard, MO;
Lisovytskiy, D;
Bandosz, TJ;
Colmenares, JC;
(2020)
Boosting the Photoactivity of Grafted Titania: Ultrasound-Driven Synthesis of a Multi-Phase Heterogeneous Nano-Architected Photocatalyst.
Advanced Functional Materials
, 31
(1)
, Article 2007115. 10.1002/adfm.202007115.
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Abstract
The herein presented low-power high-frequency (500 kHz) ultrasound-assisted precipitation synthesis (LPHF-US) leads to a unique multiphase nano-structured titanium dioxide, grafted with oxygen-containing organic functionalities. The material exhibits a high porosity (surface area 326 m2 g−1 and total pores volume 0.484 cm3 g−1) and heterogeneous surface chemistry. In the used LPHF-US synthetic protocol, the energy-demanding calcination step leading to crystallization is eliminated and an organic residue is simultaneously grafted to the surface. That organic residue affects the anatase nanocrystals, size (4–7 nm), which are embedded in an amorphous titanium hydroxide network. This nanomaterial shows superior performance as a heterogenous photocatalyst either in a gaseous phase by decomposing toxic vapors of chemical warfare agents (a mustard-gas surrogate), or in a liquid phase by selectively oxidizing benzyl alcohol, a model lignin-biomass-derived compound. The grafted organic phase enhances the catalyst's photoreactivity under visible light, by acting as a photosensitizer (antenna effect) and/or as a source of chromophores.
| Type: | Article |
|---|---|
| Title: | Boosting the Photoactivity of Grafted Titania: Ultrasound-Driven Synthesis of a Multi-Phase Heterogeneous Nano-Architected Photocatalyst |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1002/adfm.202007115 |
| Publisher version: | https://doi.org/10.1002/adfm.202007115 |
| Language: | English |
| Additional information: | This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions. |
| Keywords: | Science & Technology, Physical Sciences, Technology, Chemistry, Multidisciplinary, Chemistry, Physical, Nanoscience & Nanotechnology, Materials Science, Multidisciplinary, Physics, Applied, Physics, Condensed Matter, Chemistry, Science & Technology - Other Topics, Materials Science, Physics, biomass valorization, chemical warfare agents, heterogeneous photocatalysis, organic phase grafted titanium oxide nanoparticles, ultrasound assisted synthesis, TIO2, WATER, NANOPARTICLES, BIOMASS, ANATASE, SONOCHEMISTRY, DEGRADATION, NANOCRYSTALS, MECHANISM, OXIDATION |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Chemical Engineering |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10133263 |
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