Golveia, J; Santiago, M; Silva, L; Campos, L; Schimidt, F; (2021) Utilization of the Corncob Agro-Industrial Residue as a Potential Adsorbent in the Biosorption of Bisphenol-A. Journal of the Brazilian Chemical Society 10.21577/0103-5053.20210038. (In press).

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Abstract

The presence of plastic waste in water bodies has led to a growing concern due to the impact on human health. Among the most important plastic additive molecules is bisphenol-A (BPA). On the other hand, micro-pollutant removal processes that make use of agro-industrial waste have aroused the interest of researchers. This is because the accumulation of lignocellulosic materials is also an environmental problem. The objective of this work is to use corncob agro-industrial residue (CC) as an adsorbent in the removal of BPA in aqueous matrix. The adsorption studies were carried out in reaction media containing the ground vegetable fiber and BPA solution in concentrations of 10, 25 and 50 mg L-1, as well as at pHs 3, 5, 7 and 9. Isotherms models and kinetic models were evaluated. The results showed that CC is a potent BPA adsorbent in aqueous solution, leading to about 90% of removal. The adsorption kinetics followed the pseudo-second order model and isotherm that best suited was the Lagmuir model, and the maximum adsorption capacity was 51.25 mg per gram of adsorbent fiber, after 20 min of contact. The thermogravimetric analysis allowed us to conclude that CC is a material resistant to high temperatures, due to the presence of a considerable amount of lignin. Finally, the best results of BPA removal efficiency by CC compared to activated carbon corroborate its high biosorption capacity.

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