Arhangelskis, M;
Bučar, D-K;
Bordignon, S;
Chierotti, MR;
Stratford, SA;
Voinovich, D;
Jones, W;
(2021)
Mechanochemical reactivity inhibited, prohibited and reversed by liquid additives: examples from crystal-form screens.
Chemical Science
10.1039/d0sc05071g.
(In press).
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Abstract
We demonstrate that liquid additives can exert inhibitive or prohibitive effects on the mechanochemical formation of multi-component molecular crystals, and report that certain additives unexpectedly prompt the dismantling of such solids into physical mixtures of their constituents. Computational methods were employed in an attempt to identify possible reasons for these previously unrecognised effects of liquid additives on mechanochemical transformations.
| Type: | Article |
|---|---|
| Title: | Mechanochemical reactivity inhibited, prohibited and reversed by liquid additives: examples from crystal-form screens |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1039/d0sc05071g |
| Publisher version: | https://doi.org/10.1039/D0SC05071G |
| Language: | English |
| Additional information: | Open Access Article. This Open Access Article is licensed under a Creative Commons Attribution-Non Commercial 3.0 Unported Licence |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10120165 |
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