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Studies on ruthenium(II) and osmium(II) paracyclophane compounds

Elsegood, Mark Robert James; (1991) Studies on ruthenium(II) and osmium(II) paracyclophane compounds. Doctoral thesis (Ph.D), UCL (University College London). Green open access

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Abstract

This thesis describes studies on ruthenium(II) and osmium(II) [22]paracyclophane compounds. Chapter 1 introduces the work, giving a historical background to the development of [22]paracyclophane chemistry. The properties of this compound and the syntheses of derived metal complexes are reviewed. Chapter 2 describes the synthesis of [Os(η6-C16H16)Cl2]2. Chapter 3 reports reactions of [Ru(η6-C16H16)C12]2 which lead to the formation of binuclear triply-bridged compounds of the type [(η6-C16H16)Ru(OMe)3Ru(η6-C16H16)][X] (Y=OMe-, OEt-, OH-, Cl-). Chapter 4 presents studies on the compounds [M(η6-arene)(η6-C16H16)][X]2. Chapter 5 presents the syntheses of organometallic chain compounds containing [22]paracyclophane. Chapter 6 draws together structural and spectroscopic data on the coordinated [22]paracyclophane ligand.

Type: Thesis (Doctoral)
Qualification: Ph.D
Title: Studies on ruthenium(II) and osmium(II) paracyclophane compounds
Open access status: An open access version is available from UCL Discovery
Language: English
Additional information: Thesis digitised by ProQuest.
Keywords: Pure sciences
URI: https://discovery.ucl.ac.uk/id/eprint/10114960
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