Carden, JL;
Gierlichs, LJ;
Wass, DF;
Browne, DL;
Melen, RL;
(2018)
Unlocking the catalytic potential of tris(3,4,5-trifluorophenyl)borane with microwave irradiation.
ChemComm
, 55
(3)
pp. 318-321.
10.1039/c8cc09459d.
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Abstract
The catalytic activity of tris(3,4,5-trifluorophenyl)borane has been explored in the 1,2-hydroboration reactions of unsaturated substrates. Under conventional conditions, the borane was found to be active only in the hydroboration of aldehyde, ketone and imine substrates, with alkenes and alkynes not being reduced effectively. The use of microwave irradiation on the other hand has permitted alkenes and alkynes to be hydroborated in good yields.
| Type: | Article |
|---|---|
| Title: | Unlocking the catalytic potential of tris(3,4,5-trifluorophenyl)borane with microwave irradiation |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1039/c8cc09459d |
| Publisher version: | https://doi.org/10.1039/C8CC09459D |
| Language: | English |
| Additional information: | This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. See: https://creativecommons.org/licenses/by/3.0/ |
| Keywords: | Science & Technology, Physical Sciences, Chemistry, Multidisciplinary, Chemistry, ASYMMETRIC HYDROBORATION, IMINE HYDROBORATION, ALKENES, ALKYNES, ISOMERIZATION, PINACOLBORANE, OVENS |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > School of Life and Medical Sciences UCL > Provost and Vice Provost Offices > School of Life and Medical Sciences > Faculty of Life Sciences UCL > Provost and Vice Provost Offices > School of Life and Medical Sciences > Faculty of Life Sciences > UCL School of Pharmacy UCL > Provost and Vice Provost Offices > School of Life and Medical Sciences > Faculty of Life Sciences > UCL School of Pharmacy > Pharma and Bio Chemistry |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10114329 |
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