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Synthesis and [2+2]-photodimerisation of monothiomaleimide functionalised linear and brush-like polymers

Aljuaid, M; Liarou, E; Town, J; Baker, JR; Haddleton, DM; Wilson, P; (2020) Synthesis and [2+2]-photodimerisation of monothiomaleimide functionalised linear and brush-like polymers. Chemical Communications , 56 (66) pp. 9545-9548. 10.1039/d0cc04067c. Green open access

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Abstract

[2+2]-Photodimerisation of monothiomaleimides has been demonstrated on functionalised linear and brush-like polymers. In water/acetonitrile (95 : 5) mixtures the rate of reaction is accelerated significantly by irradiation of the thiomaleimide end group (λmax = 350 nm) with UV light, reaching full conversion within 10 minutes.

Type: Article
Title: Synthesis and [2+2]-photodimerisation of monothiomaleimide functionalised linear and brush-like polymers
Location: England
Open access status: An open access version is available from UCL Discovery
DOI: 10.1039/d0cc04067c
Publisher version: https://doi.org/10.1039/d0cc04067c
Language: English
Additional information: This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions.
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry
URI: https://discovery.ucl.ac.uk/id/eprint/10108563
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