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Structure determination of terpenes by the crystalline sponge method

Habib, F; Tocher, DA; Press, NJ; Carmalt, CJ; (2020) Structure determination of terpenes by the crystalline sponge method. Microporous and Mesoporous Materials , 308 , Article 110548. 10.1016/j.micromeso.2020.110548. Green open access

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Abstract

The crystalline sponge method was used to produce novel encapsulation complexes with the aim of structural determination of terpenes, such as geraniol-monoterpenoid, farnesol-sesquiterpenoid and β-damascone-tetraterpenoids. Along with the structure determination of the terpenoids, non-bonding CH-π, π-π interactions were identified in the host-guest complexes, which were responsible for holding the guests in the specific position with respect to the framework. In addition, the orientation of guests with respect to the framework was studied.

Type: Article
Title: Structure determination of terpenes by the crystalline sponge method
Open access status: An open access version is available from UCL Discovery
DOI: 10.1016/j.micromeso.2020.110548
Publisher version: http://dx.doi.org/10.1016/j.micromeso.2020.110548
Language: English
Additional information: This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions.
Keywords: Crystalline sponge method, Structure determination, Host-guest interactions
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry
URI: https://discovery.ucl.ac.uk/id/eprint/10107962
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