Nadeem, MA;
Idriss, H;
(2018)
Photo-thermal reactions of ethanol over Ag/TiO2 catalysts. The role of silver plasmon resonance in the reaction kinetics.
Chemical Communications
, 54
(41)
pp. 5197-5200.
10.1039/c8cc01814f.
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Abstract
Photo-thermal catalytic reactions of ethanol over Ag/TiO2 were conducted in order to probe into the role of plasmonic resonance response in the reaction kinetics. In the 300–500 K temperature domain the increase in reaction rate is found to be mainly due to changes in the activation energy while above this temperature range the increase was due to the pre-exponential factor. These results might be linked to the role of plasmonic Ag particles in polarising the reaction intermediates and therefore increasing the reaction products at temperatures up to about 500 K.
Type: | Article |
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Title: | Photo-thermal reactions of ethanol over Ag/TiO2 catalysts. The role of silver plasmon resonance in the reaction kinetics |
Open access status: | An open access version is available from UCL Discovery |
DOI: | 10.1039/c8cc01814f |
Publisher version: | https://doi.org/10.1039/c8cc01814f |
Language: | English |
Additional information: | This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. |
Keywords: | Science & Technology, Physical Sciences, Chemistry, Multidisciplinary, Chemistry, PHOTOCATALYTIC HYDROGEN-PRODUCTION, ULTRATHIN TIO2-GEL FILMS, TIO2-SUPPORTED GOLD, CATALYTIC-ACTIVITY, SURFACE, TIO2(110), NANOPARTICLES, SPECTROSCOPY, DECOMPOSITION, ADSORPTION |
UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
URI: | https://discovery.ucl.ac.uk/id/eprint/10095348 |
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