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Angle-resolved electron scattering from H2O near 0o

Kadokura, R; Loreti, A; Kover, A; Faure, A; Tennyson, J; Laricchia, G; (2019) Angle-resolved electron scattering from H2O near 0o. Physical Review Letters , 123 (3) , Article 033401. 10.1103/PhysRevLett.123.033401. Green open access

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Abstract

An electron beam, characterized by a high-angular discrimination (≃0.7°), has been used to measure the total (elastic plus inelastic) cross section of H2O in the energy range 3–100 eV. Broad coincidence is found with recent experiments, including a pronounced shoulder in the 6–12 eV region. However, at energies ≲6 eV, the present cross sections are ≃30% higher. Furthermore, forward scattering has been probed in the angular range 0°–3.5° and measures of the average (rotationally and vibrationally summed) differential elastic cross sections for incident energies ≤12 eV are obtained at a scattering angle ≃1∘. The measurements, which provide the first test of theoretical predictions in an angular region experimentally unexplored until now, are found to be within 1 standard deviation of corresponding ab initio R-matrix calculations.

Type: Article
Title: Angle-resolved electron scattering from H2O near 0o
Open access status: An open access version is available from UCL Discovery
DOI: 10.1103/PhysRevLett.123.033401
Publisher version: https://doi.org/10.1103/PhysRevLett.123.033401
Language: English
Additional information: This version is the version of record. For information on re-use, please refer to the publisher’s terms and conditions
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Physics and Astronomy
URI: https://discovery.ucl.ac.uk/id/eprint/10079101
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