Pruteanu, CG;
(2019)
The effect of deuteration on the optical spectra of compressed methane.
AIP Advances
, 9
(4)
, Article 045033. 10.1063/1.5095851.
Preview |
Text
Pruteanu_The effect of deuteration on the optical spectra of compressed methane_VoR.pdf - Published Version Download (1MB) | Preview |
Abstract
The in situ high pressure Raman spectrum of CD_{4} was found to be subtly different from its’ hydrogenous analog, CH_{4}. High quality data were obtained for the first time for pressures between 12 and 20 GPa during both fast and slow compression. Similarly to CH_{4} in phase B, CD_{4} does exhibit peak splitting in the ν_{1} (symmetric stretch) and ν_{3} (antisymmetric stretch) modes, but having the emergent shoulders present on the high-frequency side of the peaks rather than the low-frequency one as in the case of CH_{4}. The general aspect of the Raman spectrum was found to be very different from that of CH_{4}, with modes ν_{1} and ν_{3} having comparable intensities and the latter being sharper and better defined, in stark contrast to how it appears in CH_{4}.
| Type: | Article |
|---|---|
| Title: | The effect of deuteration on the optical spectra of compressed methane |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1063/1.5095851 |
| Publisher version: | https://doi.org/10.1063/1.5095851 |
| Language: | English |
| Additional information: | © Author(s) 2019. All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Earth Sciences |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10074852 |
Archive Staff Only
 |
View Item |
