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One‐step synthesis of Ag@PS nanospheres via flash nanoprecipitation

Hu, X; Zhang, Z; Lu, Y; Liu, R; Sun, L; Parkin, IP; Zhang, X; (2019) One‐step synthesis of Ag@PS nanospheres via flash nanoprecipitation. Applied Organometallic Chemistry , 33 (3) , Article e4713. 10.1002/aoc.4713. Green open access

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Abstract

In the work reported, we utilized a facile flash nanoprecipitation process to generate Ag nanoparticles@nanospheres polymer composites. Ag nanoparticles can be loaded onto the polymeric polystyrene (PS) nanosphere surface using a simple and inexpensive method through in situ growth; the amount of loaded Ag nanoparticles and the size of holes on the PS surface prepared by flash nanoprecipitation can be fine‐tuned by changing the pH of the water medium and the PS nanoparticles should have a greater specific area. The as‐synthesized Ag@PS composite nanoparticles obtained via the one‐step and continuous preparation route show high catalytic activity in the reduction reaction of 4‐nitrophenol. Importantly, the nanoparticles show no loss of catalytic performance over five cycles.

Type: Article
Title: One‐step synthesis of Ag@PS nanospheres via flash nanoprecipitation
Open access status: An open access version is available from UCL Discovery
DOI: 10.1002/aoc.4713
Publisher version: https://doi.org/10.1002/aoc.4713
Language: English
Additional information: This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions.
Keywords: Ag@polymeric polystyrene, catalytic, flash nanoprecipitation, nanoparticles
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
URI: https://discovery.ucl.ac.uk/id/eprint/10074612
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