Vázquez-Galván, J; Flox, C; Jervis, JR; Jorge, AB; Shearing, PR; Morante, JR; (2019) High-power nitrided TiO2 carbon felt as the negative electrode for all-vanadium redox flow batteries. Carbon , 148 pp. 91-104. 10.1016/j.carbon.2019.01.067.

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Abstract

This work describes the design of an electrode with enhanced performance applied to all-vanadium redox flow batteries (VRFBs). This new electrode consists of a structural porous carbon felt decorated with TiO 2 rutile nanoparticles, which has been nitrided using ammonolysis at 900 °C. An outstanding charge and mass transfer over the electrode-electrolyte interface was observed as a consequence of the synergetic effect of N- and O-functionalization over carbon felt (CF) and the partial formation of TiN (metallic conductor) phase. Moreover, this material has not only improved in terms of catalysis towards the V 3+ /V 2+ redox reaction (k 0 = 1.6 × 10 −3 cm s −1 ), but also inhibited the hydrogen evolution reaction (HER), which is one of the main causes of imbalances that lead to battery failure. This led to an impressive high-power peak output value up to 700 mW cm −2 , as well as work at high current density in galvanostatic conditions (i.e. 150 mA cm −2 ), exhibiting low ohmic losses (overpotential) and great redox single cell reversibility, with a superior energy efficiency of 71%. An inexpensive, earth abundant and scalable synthesis method to boost VRFBs technology based on nitrided CF@TiO 2 is presented, being able to overcome certain constrains, and therefore to achieve high energy and power densities.

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