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Magnetic structure and spin-wave excitations in the multiferroic magnetic metal-organic framework

Walker, HC; Duncan, HD; Le, MD; Keen, DA; Voneshen, DJ; Phillips, AE; (2017) Magnetic structure and spin-wave excitations in the multiferroic magnetic metal-organic framework. Physical Review B , 96 (9) , Article 094423. 10.1103/PhysRevB.96.094423. Green open access

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Abstract

We report the magnetic diffraction pattern and spin-wave excitations in (CD3)2ND2[Mn(DCO2)3] measured using elastic and inelastic neutron scattering. The magnetic structure is shown to be a G-type antiferromagnet with moments pointing along the b axis. By comparison with simulations based on linear spin-wave theory, we have developed a model for the magnetic interactions in this multiferroic metal-organic framework material. The interactions form a three-dimensional network with antiferromagnetic nearest-neighbor interactions along three directions of J1 = −0.103(8) meV, J2 = −0.032(8) meV, and J3 = −0.035(8) meV.

Type: Article
Title: Magnetic structure and spin-wave excitations in the multiferroic magnetic metal-organic framework
Open access status: An open access version is available from UCL Discovery
DOI: 10.1103/PhysRevB.96.094423
Publisher version: https://doi.org/10.1103/PhysRevB.96.094423
Language: English
Additional information: This version is the version of record. For information on re-use, please refer to the publisher’s terms and conditions.
UCL classification: UCL
UCL > Provost and Vice Provost Offices
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry
URI: https://discovery.ucl.ac.uk/id/eprint/10070867
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