Zorlu, Y;
Erbahar, D;
Çetinkaya, A;
Bulut, A;
Erkal, TS;
Yazaydin, AO;
Beckmann, J;
(2019)
A cobalt arylphosphonate MOF – superior stability, sorption and magnetism.
Chemical Communication
, 55
(21)
pp. 3053-3056.
10.1039/c8cc09655d.
Preview |
Text
Yazaydin_A cobalt arylphosphonate MOF - superior stability, sorption and magnetism_template_AAM.pdf - Accepted Version Download (474kB) | Preview |
Abstract
We report a novel metal-organic framework (MOF) based on a cobalt arylphosphonate, namely, [Co₂(H₄-MTPPA)]·3NMP·H₂O (1·3NMP·H₂O), which was prepared solvothermically from the tetrahedral linker tetraphenylmethane tetrakis-4-phosphonic acid (H₈-MTPPA) and CoSO₄·7H₂O in N-methyl-2-pyrrolidone (NMP). Compound 1 has the highest porosity (BET surface area of 1034 m² g⁻¹) ever reported for a MOF based on an aryl phosphonic acid linker. The indigo blue crystals of 1·3NMP·H₂O are composed of edge-shared eight-membered Co₂P₂O₄ rings, and are thermally very stable up to 500 °C.
| Type: | Article |
|---|---|
| Title: | A cobalt arylphosphonate MOF – superior stability, sorption and magnetism |
| Location: | England |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1039/c8cc09655d |
| Publisher version: | http://dx.doi.org/10.1039/c8cc09655d |
| Language: | English |
| Additional information: | This version is the version of record. For information on re-use, please refer to the publisher’s terms and conditions. |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Chemical Engineering |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10068245 |
Archive Staff Only
 |
View Item |
