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Mode i interlaminar fracture toughness of carbon nanotube web-modified polymer composites

Chitwan, R; Nistal, A; Falzon, BG; Hawkins, SC; (2017) Mode i interlaminar fracture toughness of carbon nanotube web-modified polymer composites. In: Proceedings of the 21st International Conference on Composites Materials (ICCM-21). (pp. p. 4133). ICCM: Xi'an, China. Green open access

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Abstract

Carbon nanotube ‘webs’ (CNTWs) are used as interlayers between marine grade (HMC/SE84LV) and aerospace grade (IM7/977-2) carbon fibre-reinforced polymer (CFRP) composite laminates to explore their influence on mode I interlaminar fracture toughness (ILFT). Inserting CNTW in SE84LV laminates improves the mode I ILFT by 4% whereas inserting CNTW in 977-2 laminates reduces the mode I ILFT by 85%. Fractography and interfacial analysis show that SE84LV resin penetrated and adequately wetted the CNTW whereas 977-2 resin failed to penetrate and wet the CNTW which resulted in large void formation and created a weak interlaminar region. To counter the poor penetration of 977-2 resin, CNTW was impregnated with neat 977-2 resin prior to its insertion in the prepreg layup. Inserting preimpregnated CNTW resulted in a 68% reduction in mode I ILFT. It is proposed that the reduction in mode I ILFT of IM7/977-2 system interleaved with CNTW was due to the restricted resin mobility in the CNTW region and the poor interaction between CNTW and 977-2 resin. The 977-2 remains at minimum viscosity for a shorter time than SE84LV. Remaining at low viscosity for a longer period allows the resin to flow in the CNTW region. The weak interaction between CNTW and the 977-2 resin is discussed in terms of the polarity of the constituent polymer molecules. 977-2 is more polar than SE84LV thus has a very low affinity to interact with CNTW.

Type: Proceedings paper
Title: Mode i interlaminar fracture toughness of carbon nanotube web-modified polymer composites
Event: 21st International Conference on Composites Materials (ICCM-21)
Open access status: An open access version is available from UCL Discovery
Publisher version: http://www.iccm-central.org/Proceedings/ICCM21proc...
Language: English
Additional information: This version is the version of record. For information on re-use, please refer to the publisher’s terms and conditions.
Keywords: Carbon nanotube web, interlaminar fracture toughness, Toughened epoxy resin, Multifunctional hierarchical composites.
UCL classification: UCL
UCL > Provost and Vice Provost Offices
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > MAPS Faculty Office
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > MAPS Faculty Office > Institute for Materials Discovery
URI: https://discovery.ucl.ac.uk/id/eprint/10059411
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