Chen, W;
Bakewell, C;
Crimmin, M;
(2017)
Functionalisation of Carbon–Fluorine Bonds with Main Group Reagents.
Synthesis
, 49
(04)
pp. 810-821.
10.1055/s-0036-1588663.
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58. Functionalisation of sp2Carbon–Fluorine Bonds with Main Group Reagents_14thOct.pdf - Accepted Version Download (4MB) | Preview |
Abstract
Synthetic approaches to produce reactive chemical building blocks from fluorinated molecules by the functionalization of carbon–fluorine bonds with main group reagents are reviewed. The reaction types can be categorized as: (i) the formal 1,2-addition of C–F bonds across Si–Si, B–B, or Mg–Mg bonds; (ii) the oxidative addition of C–F bonds to Si(II), Ge(II), and Al(I) centres; and (iii) the dehydrogenative coupling of C–F bonds with Al–H or B–H bonds. Many of the advances have emerged between 2015–2016 and are largely focused upon aromatic substrates that contain sp2 C–F bonds.
| Type: | Article |
|---|---|
| Title: | Functionalisation of Carbon–Fluorine Bonds with Main Group Reagents |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1055/s-0036-1588663 |
| Publisher version: | http://dx.doi.org/10.1055/s-0036-1588663 |
| Language: | English |
| Additional information: | This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions. |
| Keywords: | fluorine - carbon–fluorine - functionalisation - borylation - silylation - alumination - magnesiation |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10057996 |
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