Bakewell, C;
White, AJP;
Crimmin, MR;
(2016)
Addition of Carbon–Fluorine Bonds to a Mg(I)–Mg(I) Bond: An Equivalent of Grignard Formation in Solution.
Journal of the American Chemical Society
, 138
(39)
pp. 12763-12766.
10.1021/jacs.6b08104.
Preview |
Text
Bakewell_Addition of Carbon–Fluorine Bonds to a Mg(I)–Mg(I) Bond. An Equivalent of Grignard Formation in Solution_VoR.pdf - Published Version Download (1MB) | Preview |
Abstract
Addition of the carbon–fluorine bond of a series of perfluorinated and polyfluorinated arenes across the Mg–Mg bond of a simple coordination complex proceeds rapidly in solution. The reaction results in the formation of a new carbon–magnesium bond and a new fluorine–magnesium bond and is analogous to Grignard formation in homogeneous solution.
| Type: | Article |
|---|---|
| Title: | Addition of Carbon–Fluorine Bonds to a Mg(I)–Mg(I) Bond: An Equivalent of Grignard Formation in Solution |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1021/jacs.6b08104 |
| Publisher version: | http://doi.org/10.1021/jacs.6b08104 |
| Language: | English |
| Additional information: | © 2016 American Chemical Society. ACS AuthorChoice - This is an open access article published under a Creative Commons Attribution (CC-BY) License (https://creativecommons.org/licenses/by/4.0/). |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10057625 |
Archive Staff Only
 |
View Item |
