Jia, J;
White, ER;
Clancy, AJ;
Rubio Carrero, N;
Suter, T;
Miller, TS;
McMillan, PM;
... Shaffer, M; + view all
(2018)
Fast Exfoliation and Functionalisation of Two‐Dimensional Crystalline Carbon Nitride by Framework Charging.
Angewandte Chemie International Edition
, 57
(39)
pp. 12656-12660.
10.1002/anie.201800875.
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Abstract
2D layered graphitic carbon nitride nanosheets offer tunable electronic and chemical properties. However, exfoliation and functionalisation of gCN for specific applications remains challenging. We report a scalable one-pot reductive method to produce solutions of single and few layer 2D gCN nanosheets with excellent stability in a high mass yield (35%) from polytriazine imide. High resolution imaging confirms the intact crystalline structure and identifies an AB stacking. The first successful deliberate organic functionalisation of dissolved gCN is illustrated, providing a general route to adjust their properties.
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