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Electron-Promoted Desorption from Water Ice Surfaces: Neutral Gas Phase Products

Abdulgalil, AGM; Rosu-Finsen, A; Marchione, D; Thrower, JD; Collings, MP; McCoustra, MRS; (2017) Electron-Promoted Desorption from Water Ice Surfaces: Neutral Gas Phase Products. ACS Earth and Space Chemistry , 1 (4) pp. 209-215. 10.1021/acsearthspacechem.7b00028. Green open access

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Abstract

Electron-promoted desorption (EPD) from compact amorphous solid water (c-ASW) has been studied. Low-energy electron bombardment with 200–300 eV electrons leads to H2O depletion, as monitored by reflection–absorption infrared spectroscopy (RAIRS) of the remaining c-ASW film. Cross sections for H2O depletion were calculated to be in the range from 1.6 ± 1.0 × 10–16 to 5.2 ± 3.0 × 10–16 cm2. However, mass spectrometric measurements identify a major component of the desorbing material as H2, which appears with kinetics similar to those for H2O loss. Molecular H2O is observed as a minor desorption product in the gas phase.

Type: Article
Title: Electron-Promoted Desorption from Water Ice Surfaces: Neutral Gas Phase Products
Open access status: An open access version is available from UCL Discovery
DOI: 10.1021/acsearthspacechem.7b00028
Publisher version: http://dx.doi.org/10.1021/acsearthspacechem.7b0002...
Language: English
Additional information: This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions.
Keywords: electron irradiation; H2O; ISM; molecular cloud; non-thermal desorption
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry
URI: https://discovery.ucl.ac.uk/id/eprint/10054090
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