Steed, JW;
Tocher, DA;
(2018)
Dynamic behaviour in nicotinate-bridged binuclear ruthenium(IV) complexes.
Polyhedron
, 147
pp. 152-155.
10.1016/j.poly.2018.03.025.
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Abstract
The isonicotinic acid adduct [Ru(η3:η3-C10H16)Cl2(p-NC5H4CO2H)] 1 and nicotinate and isonicotinate bridged binuclear complexes [Ru2(η3:η3-C10H16)2Cl3(μ-κN,O,O′-NC5H4CO2)] 2 and 3 are reported. Complexes 2 and 3 exist as mixtures of diastereoisomers and are dynamic in water saturated chloroform solution with complexes involving bidentate chelating carboxylate ligands in equilibrium with unidente carboxylate aquo complexes [Ru2(η3:η3-C10H16)2Cl3(OH2)(μ-κN,O-NC5H4CO2)].
| Type: | Article |
|---|---|
| Title: | Dynamic behaviour in nicotinate-bridged binuclear ruthenium(IV) complexes |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1016/j.poly.2018.03.025 |
| Publisher version: | http://dx.doi.org/10.1016/j.poly.2018.03.025 |
| Language: | English |
| Additional information: | This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions. |
| Keywords: | Ruthenium(IV), Bis(allyl), Carboxylate, Bridged, Nicotinic acid |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10049450 |
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