Li, Y;
(2018)
Heterostructured WO3@CoWO4 bilayer nanosheets for enhanced visible-light photo, electro and photoelectro-chemical oxidation of water.
Journal of Materials Chemistry A
, 6
(15)
pp. 6111-6690.
10.1039/C8TA00555A.
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Abstract
Herein, a facile interface-induced synthesis method is first established to newly fabricate two-dimensional (2D) bilayer nanosheets of WO3@CoWO4 as highly efficient catalysts for enhanced photo, electro and photoelectro-chemical oxygen evolution reactions (OERs). The heterostructure and the interfacial oxygen vacancy of WO3@CoWO4 reduce the energy barriers in OER. Density functional theory (DFT) calculations and material characterizations reveal that WO3@CoWO4 p-n heterojunction endows the composite with a narrowed band gap for better visible-light harvesting, rapid charge transfer across the interface and a lower recombination rate of the photo-excited carriers. The interface O-vacancy vests the active Co site with an enhanced density of state (DOS) at valence band maximum (VBM), which can increase the concentration of the photogenerated holes to improve photocatalytic and photoelectrochemical (PEC) activity. This study presents a proof-of-concept design towards low cost and multi-metal 2D/2D nanosheets for water oxidation applications.
| Type: | Article |
|---|---|
| Title: | Heterostructured WO3@CoWO4 bilayer nanosheets for enhanced visible-light photo, electro and photoelectro-chemical oxidation of water |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1039/C8TA00555A |
| Publisher version: | http://dx.doi.org/10.1039/C8TA00555A |
| Language: | English |
| Additional information: | © The Royal Society of Chemistry 2018. Open Access. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material. |
| UCL classification: | UCL > Provost and Vice Provost Offices UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Earth Sciences |
| URI: | https://discovery.ucl.ac.uk/id/eprint/10044437 |
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