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Applying a potential difference to minimise damage to carbon fibres during carbon nanotube grafting by chemical vapour deposition

Anthony, DB; Qian, H; Clancy, AJ; Greenhalgh, ES; Bismarck, A; Shaffer, MSP; (2017) Applying a potential difference to minimise damage to carbon fibres during carbon nanotube grafting by chemical vapour deposition. Nanotechnology , 28 , Article 305602. 10.1088/1361-6528/aa783f. Green open access

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Abstract

The application of an in situ potential difference between carbon fibres and a graphite foil counter electrode (300 V, generating an electric field ca 0.3-0.7 V μm(-1)), during the chemical vapour deposition synthesis of carbon nanotube (CNT) grafted carbon fibres, significantly improves the uniformity of growth without reducing the tensile properties of the underlying carbon fibres. Grafted CNTs with diameters 55 nm ± 36 nm and lengths around 10 μm were well attached to the carbon fibre surface, and were grown without the requirement for protective barrier coatings. The grafted CNTs increased the surface area to 185 m(2) g(-1) compared to the as-received sized carbon fibre 0.24 m(2) g(-1). The approach is not restricted to batch systems and has the potential to improve CNT grafted carbon fibre production for continuous processing.

Type: Article
Title: Applying a potential difference to minimise damage to carbon fibres during carbon nanotube grafting by chemical vapour deposition
Location: England
Open access status: An open access version is available from UCL Discovery
DOI: 10.1088/1361-6528/aa783f
Publisher version: https://doi.org/10.1088/1361-6528/aa783f
Language: English
Additional information: Original content from this work may be used under the terms of the Creative Commons Attribution 3.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry
URI: https://discovery.ucl.ac.uk/id/eprint/10025079
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