TY - JOUR VL - 96 UR - http://dx.doi.org/10.1103/PhysRevLett.96.146101 A1 - Schnadt, J A1 - Michaelides, A A1 - Knudsen, J A1 - Vang, RT A1 - Reuter, K A1 - Laegsgaard, E A1 - Scheffler, M A1 - Besenbacher, F AV - public JF - PHYS REV LETT N2 - Scanning tunneling microscopy (STM) and density-functional theory are used to reexamine the structure of the renowned p(4x4)-O/Ag(111) surface oxide. The accepted structural model [C. I. Carlisle , Phys. Rev. Lett. 84, 3899 (2000)] is incompatible with the enhanced resolution of the current STM measurements. An "Ag-6 model" is proposed that is more stable than its predecessor and accounts for the coexistence of the p(4x4) and a novel c(3x5 root 3)rect phase. This coexistence is an indication of the dynamic complexity of the system that until now has not been appreciated. KW - OXYGEN KW - CHEMISORPTION KW - MICROSCOPE KW - TRANSITION KW - ADSORPTION KW - INSIGHTS KW - FILM ID - discovery9326 IS - 14 N1 - © 2006 The American Physical Society PB - AMERICAN PHYSICAL SOC TI - Revisiting the structure of the p(4x4) surface oxide on Ag(111) SN - 0031-9007 Y1 - 2006/04/14/ ER -