eprintid: 59610
rev_number: 33
eprint_status: archive
userid: 608
dir: disk0/00/05/96/10
datestamp: 2010-10-16 12:12:28
lastmod: 2020-06-10 19:00:57
status_changed: 2010-10-16 12:12:28
type: article
metadata_visibility: show
item_issues_count: 0
creators_name: Stoneham, AM
creators_name: Ramos, MMD
title: Equilibria and Electronic Processes
ispublished: pub
subjects: 11050
divisions: UCL
divisions: A01
divisions: B04
divisions: C06
keywords: CHARGE-STATE STABILITY, POTENTIALS
note: Text made available to UCL Discovery by kind permission of Elsevier B.V., 2012
abstract: The operation of solid-state gas sensors and of certain types of catalyst depends on the energy of free carriers in one phase relative to some state in another medium. Here special problems arise in determining the electron affinity of ionic crystals. These are discussed, together with some of the issues which cause similar problems in different types of systems, here including aqueous solutions and conducting polymers. For ionic solids, knowledge of which charge states are stable for substitutional transition metal ions gives a powerful tool, giving predictions in accordance with electrochemical data. It appears that MgO has a negative electron affinity.
date: 1993-09
publisher: ACADEMIC PRESS INC JNL-COMP SUBSCRIPTIONS
official_url: http://dx.doi.org/10.1006/jssc.1993.1259
vfaculties: VMPS
oa_status: green
language: eng
primo: open
primo_central: open_green
article_type_text: Article
verified: verified_manual
doi: 10.1006/jssc.1993.1259
language_elements: EN
lyricists_name: STONEHAM, ARTHUR
lyricists_id: AMSTO63
full_text_status: public
publication: Journal of Solid State Chemistry
volume: 106
number: 1
pagerange: 2 - 12
issn: 0022-4596
citation:        Stoneham, AM;    Ramos, MMD;      (1993)    Equilibria and Electronic Processes.                   Journal of Solid State Chemistry , 106  (1)   2 - 12.    10.1006/jssc.1993.1259 <https://doi.org/10.1006/jssc.1993.1259>.       Green open access   
 
document_url: https://discovery.ucl.ac.uk/id/eprint/59610/1/59610.pdf