eprintid: 46163 rev_number: 39 eprint_status: archive userid: 608 dir: disk0/00/04/61/63 datestamp: 2010-10-15 18:58:28 lastmod: 2020-02-12 17:59:42 status_changed: 2012-08-07 13:35:34 type: article metadata_visibility: show item_issues_count: 0 creators_name: Shields, GA title: A normalised seawater strontium isotope curve: possible implications for Neoproterozoic-Cambrian weathering rates and the further oxygenation of the Earth ispublished: pub divisions: UCL divisions: A01 divisions: B04 divisions: C06 divisions: F57 note: © Author(s) 2007. This work is licensed under a Creative Commons License. For more information see http://creativecommons.org/licenses/by-nc-sa/2.0/deed.en abstract: The strontium isotope composition of seawater is strongly influenced on geological time scales by changes in the rates of continental weathering relative to ocean crust alteration. However, the potential of the seawater 87Sr/86Sr curve to trace globally integrated chemical weathering rates has not been fully realised because ocean 87Sr/86Sr is also influenced by the isotopic evolution of Sr sources to the ocean. A preliminary attempt is made here to normalise the seawater 87Sr/86Sr curve to plausible trends in the 87Sr/86Sr ratios of the three major Sr sources: carbonate dissolution, silicate weathering and submarine hydrothermal exchange. The normalised curve highlights the Neoproterozoic-Phanerozoic transition as a period of exceptionally high continental influence, indicating that this interval was characterised by a transient increase in global weathering rates and/or by the weathering of unusually radiogenic crustal rocks. Close correlation between the normalised 87Sr/86Sr curve, a published seawater δ34S curve and atmospheric pCO2 models is used here to argue that elevated chemical weathering rates were a major contributing factor to the steep rise in seawater 87Sr/86Sr from 650 Ma to 500 Ma. Elevated weathering rates during the Neoproterozoic-Cambrian interval led to increased nutrient availability, organic burial and to the further oxygenation of Earth's surface environment. Use of normalised seawater 87Sr/86Sr curves will, it is hoped, help to improve future geochemical models of Earth System dynamics. date: 2007-07 official_url: http://www.electronic-earth.net/2/35/2007/ee-2-35-2007.html vfaculties: VMPS oa_status: green language: eng primo: open primo_central: open_green article_type_text: Article verified: verified_manual elements_source: Manually entered elements_id: 98785 lyricists_name: Shields, Graham lyricists_id: GASHI56 full_text_status: public publication: eEarth volume: 2 pagerange: 35 - 42 issn: 1815-381X citation: Shields, GA; (2007) A normalised seawater strontium isotope curve: possible implications for Neoproterozoic-Cambrian weathering rates and the further oxygenation of the Earth. eEarth , 2 35 - 42. Green open access document_url: https://discovery.ucl.ac.uk/id/eprint/46163/1/46163_Shields_2007_eEarth.pdf