TY - JOUR A1 - Wang, SX A1 - Acha, D A1 - Shah, AJ A1 - Hills, F A1 - Roitt, I A1 - Demosthenous, A A1 - Bayford, RH KW - Alzheimer's disease; Biomarker; Electrochemical biosensor; Impedance; Tau JF - Biosensors and Bioelectronics UR - http://dx.doi.org/10.1016/j.bios.2016.10.077 SN - 0956-5663 N2 - This study presents a novel approach based on a four-electrode electrochemical biosensor for the detection of tau protein ? one of the possible markers for the prediction of Alzheimer's disease (AD). The biosensor is based on the formation of stable antibody?antigen complexes on gold microband electrodes covered with a layer of a self-assembled monolayer and protein G. Antibodies were immobilized on the gold electrode surface in an optimal orientation by protein G interaction. Electrochemical impedance spectroscopy was used to analyze impedance change, which revealed a linear response with increasing tau concentrations. The assay is fast (<1 h for incubation and measurement) and very sensitive. The limit of quantification for the full-length 2N4R tau protein is 0.03 pM, a value unaltered when the assay was processed in bovine serum albumin or human serum. This technology could be adapted for the detection of other biomarkers to provide a multiple assay to identify AD progression in a point of care setting. ID - discovery1527523 N1 - Copyright © 2016. This manuscript version is published under a Creative Commons Attribution Non-commercial Non-derivative 4.0 International licence (CC BY-NC-ND 4.0). This licence allows you to share, copy, distribute and transmit the work for personal and non-commercial use providing author and publisher attribution is clearly stated. Further details about CC BY licences are available at http://creativecommons.org/licenses/by/4.0. Access may be initially restricted by the publisher. AV - public SP - 482 VL - 92 Y1 - 2017/06/15/ EP - 488 TI - Detection of the tau protein in human serum by a sensitive four-electrode electrochemical biosensor ER -