<> <http://www.w3.org/2000/01/rdf-schema#comment> "The repository administrator has not yet configured an RDF license."^^<http://www.w3.org/2001/XMLSchema#string> . <> <http://xmlns.com/foaf/0.1/primaryTopic> <https://discovery.ucl.ac.uk/id/eprint/1523325> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://purl.org/ontology/bibo/Article> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/dc/terms/title> "Immobilisation of caesium in magnesium phosphate-based blends"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/ontology/bibo/abstract> "Disposal of Caesium (Cs) by incorporating it into host matrices has been proved as a promising concept.\r\nEven though Portland cement (PC) based systems can be used to encapsulate low (LLW) or intermediate\r\nlevel waste (ILW), they are not efficient for immobilising Cs due to the very high water-solubility of Cs.\r\nMagnesium phosphate cement (MPC), a chemically bonded ceramic consists of struvite families produced by\r\nthe acid based reactions between dead-burnt magnesium oxide (MgO) and phosphates (e.g., KH2PO4), can\r\nbe a potential candidate for hosting Cs, since it has been reported that Cs can be incorporated in the Kstruvite\r\nstructures by substituting potassium (K) to form (K,Cs)-struvite. However, the acid-based reaction to\r\nform MPC under ambient temperature between magnesium oxide (MgO) and phosphates (e.g., KH2PO4) is\r\nviolent and exothermic, which raises concerns about industrial application of MPC in real world. In this work,\r\nground-granulated blast-furnace slag (GGBS) and pulverised fuel ash were used to replace MPC in order to\r\nreduce the heat released. The feasibility of MPC, as well as MPC-based blends, i.e. GGBS-MPC or PFAMPC\r\nmatrices, for immobilising Cs was assessed by their leaching behaviour at the ages of 3d, 7d and 28d.\r\nIn addition, two typical PC based systems currently used in nuclear waste immobilisation, i.e., pure PC and\r\nPC-GGBS (1:9) mixes, were also produced and tested as controls. The results indicated that all the MPC\r\nmixes, including pure MPC, GGBS-MPC and PFA-MPC, demonstrated superb capability for immobilising Cs,\r\nwith the immobilisation rates achieved more than 99.5% at all curing age investigated. Compared to the\r\ntraditional PC and PC/GGBS mixes, the MPC mixes nearly doubled the Cs immobilisation rate, which is\r\nrather encouraging."^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/dc/terms/date> "2016-09-05" . <https://discovery.ucl.ac.uk/id/document/383807> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://purl.org/ontology/bibo/Document> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/ontology/bibo/volume> "36" . <https://discovery.ucl.ac.uk/id/org/ext-c1156d5712485d9910a2121af2365ed6> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Organization> . <https://discovery.ucl.ac.uk/id/org/ext-c1156d5712485d9910a2121af2365ed6> <http://xmlns.com/foaf/0.1/name> "The Institute of Materials, Minerals and Mining"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/dc/terms/publisher> <https://discovery.ucl.ac.uk/id/org/ext-c1156d5712485d9910a2121af2365ed6> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/ontology/bibo/status> <http://purl.org/ontology/bibo/status/published> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-0e8be888150f599365a5c479b548e9f7> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> . <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_1> <https://discovery.ucl.ac.uk/id/person/ext-0e8be888150f599365a5c479b548e9f7> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-2a203e85ea327be84ef0403c9c55815c> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> . <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_2> <https://discovery.ucl.ac.uk/id/person/ext-2a203e85ea327be84ef0403c9c55815c> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-5afd07bf4473f673768041b98d006fe4> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> . <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_3> <https://discovery.ucl.ac.uk/id/person/ext-5afd07bf4473f673768041b98d006fe4> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-8f60367d5e3460bfe833273967bf33ba> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> . <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_4> <https://discovery.ucl.ac.uk/id/person/ext-8f60367d5e3460bfe833273967bf33ba> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-305579ac4db198424dadfa672010354f> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> . <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_5> <https://discovery.ucl.ac.uk/id/person/ext-305579ac4db198424dadfa672010354f> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-58d4df77a633a5fc0d020cb812e399e4> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> . <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_6> <https://discovery.ucl.ac.uk/id/person/ext-58d4df77a633a5fc0d020cb812e399e4> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-de668088c8b6856f49e79359463f14fa> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> . <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_7> <https://discovery.ucl.ac.uk/id/person/ext-de668088c8b6856f49e79359463f14fa> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-8d96bcc16664f59d509b8056d12232f0> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> . <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_8> <https://discovery.ucl.ac.uk/id/person/ext-8d96bcc16664f59d509b8056d12232f0> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-70700883c66e7071122599e3c8342164> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> . <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_9> <https://discovery.ucl.ac.uk/id/person/ext-70700883c66e7071122599e3c8342164> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-b2069eb448d119587336807040862eb8> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> . <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_10> <https://discovery.ucl.ac.uk/id/person/ext-b2069eb448d119587336807040862eb8> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-93097afa860aea8261ee7e9ab0290d1e> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> . <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_11> <https://discovery.ucl.ac.uk/id/person/ext-93097afa860aea8261ee7e9ab0290d1e> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-5ae6cf8a9e3a84e64a2e0e981dbd6bd1> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> . <https://discovery.ucl.ac.uk/id/eprint/1523325#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_12> <https://discovery.ucl.ac.uk/id/person/ext-5ae6cf8a9e3a84e64a2e0e981dbd6bd1> . <https://discovery.ucl.ac.uk/id/person/ext-8f60367d5e3460bfe833273967bf33ba> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-8f60367d5e3460bfe833273967bf33ba> <http://xmlns.com/foaf/0.1/givenName> "L"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-8f60367d5e3460bfe833273967bf33ba> <http://xmlns.com/foaf/0.1/familyName> "Li"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-8f60367d5e3460bfe833273967bf33ba> <http://xmlns.com/foaf/0.1/name> "L Li"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-58d4df77a633a5fc0d020cb812e399e4> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-58d4df77a633a5fc0d020cb812e399e4> <http://xmlns.com/foaf/0.1/givenName> "C"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-58d4df77a633a5fc0d020cb812e399e4> <http://xmlns.com/foaf/0.1/familyName> "You"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-58d4df77a633a5fc0d020cb812e399e4> <http://xmlns.com/foaf/0.1/name> "C You"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-5afd07bf4473f673768041b98d006fe4> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-5afd07bf4473f673768041b98d006fe4> <http://xmlns.com/foaf/0.1/givenName> "Y"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-5afd07bf4473f673768041b98d006fe4> <http://xmlns.com/foaf/0.1/familyName> "Bai"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-5afd07bf4473f673768041b98d006fe4> <http://xmlns.com/foaf/0.1/name> "Y Bai"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-70700883c66e7071122599e3c8342164> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-70700883c66e7071122599e3c8342164> <http://xmlns.com/foaf/0.1/givenName> "F"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-70700883c66e7071122599e3c8342164> <http://xmlns.com/foaf/0.1/familyName> "Jin"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-70700883c66e7071122599e3c8342164> <http://xmlns.com/foaf/0.1/name> "F Jin"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-de668088c8b6856f49e79359463f14fa> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-de668088c8b6856f49e79359463f14fa> <http://xmlns.com/foaf/0.1/givenName> "J"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-de668088c8b6856f49e79359463f14fa> <http://xmlns.com/foaf/0.1/familyName> "Qian"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-de668088c8b6856f49e79359463f14fa> <http://xmlns.com/foaf/0.1/name> "J Qian"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-5ae6cf8a9e3a84e64a2e0e981dbd6bd1> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-5ae6cf8a9e3a84e64a2e0e981dbd6bd1> <http://xmlns.com/foaf/0.1/givenName> "M"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-5ae6cf8a9e3a84e64a2e0e981dbd6bd1> <http://xmlns.com/foaf/0.1/familyName> "Deng"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-5ae6cf8a9e3a84e64a2e0e981dbd6bd1> <http://xmlns.com/foaf/0.1/name> "M Deng"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-0e8be888150f599365a5c479b548e9f7> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-0e8be888150f599365a5c479b548e9f7> <http://xmlns.com/foaf/0.1/givenName> "Y"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-0e8be888150f599365a5c479b548e9f7> <http://xmlns.com/foaf/0.1/familyName> "Yue"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-0e8be888150f599365a5c479b548e9f7> <http://xmlns.com/foaf/0.1/name> "Y Yue"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-305579ac4db198424dadfa672010354f> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-305579ac4db198424dadfa672010354f> <http://xmlns.com/foaf/0.1/givenName> "J"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-305579ac4db198424dadfa672010354f> <http://xmlns.com/foaf/0.1/familyName> "Song"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-305579ac4db198424dadfa672010354f> <http://xmlns.com/foaf/0.1/name> "J Song"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-8d96bcc16664f59d509b8056d12232f0> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-8d96bcc16664f59d509b8056d12232f0> <http://xmlns.com/foaf/0.1/givenName> "C"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-8d96bcc16664f59d509b8056d12232f0> <http://xmlns.com/foaf/0.1/familyName> "McCague"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-8d96bcc16664f59d509b8056d12232f0> <http://xmlns.com/foaf/0.1/name> "C McCague"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-b2069eb448d119587336807040862eb8> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-b2069eb448d119587336807040862eb8> <http://xmlns.com/foaf/0.1/givenName> "A"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-b2069eb448d119587336807040862eb8> <http://xmlns.com/foaf/0.1/familyName> "Al-Tabbaa"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-b2069eb448d119587336807040862eb8> <http://xmlns.com/foaf/0.1/name> "A Al-Tabbaa"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-93097afa860aea8261ee7e9ab0290d1e> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-93097afa860aea8261ee7e9ab0290d1e> <http://xmlns.com/foaf/0.1/givenName> "L"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-93097afa860aea8261ee7e9ab0290d1e> <http://xmlns.com/foaf/0.1/familyName> "Mo"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-93097afa860aea8261ee7e9ab0290d1e> <http://xmlns.com/foaf/0.1/name> "L Mo"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-2a203e85ea327be84ef0403c9c55815c> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-2a203e85ea327be84ef0403c9c55815c> <http://xmlns.com/foaf/0.1/givenName> "Q"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-2a203e85ea327be84ef0403c9c55815c> <http://xmlns.com/foaf/0.1/familyName> "Zhou"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-2a203e85ea327be84ef0403c9c55815c> <http://xmlns.com/foaf/0.1/name> "Q Zhou"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://purl.org/ontology/bibo/Article> . <https://discovery.ucl.ac.uk/id/eprint/1523325> <http://purl.org/ontology/bibo/presentedAt> <https://discovery.ucl.ac.uk/id/event/ext-b289483586b2b2a85e6ef7056cad3d49> . <https://discovery.ucl.ac.uk/id/event/ext-b289483586b2b2a85e6ef7056cad3d49> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://purl.org/ontology/bibo/Conference> . <https://discovery.ucl.ac.uk/id/event/ext-b289483586b2b2a85e6ef7056cad3d49> <http://purl.org/dc/terms/title> "36th Cement and Concrete Science 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