TY  - JOUR
KW  - Science & Technology
KW  -  Physical Sciences
KW  -  Chemistry
KW  -  Physical
KW  -  Physics
KW  -  Atomic
KW  -  Molecular & Chemical
KW  -  Chemistry
KW  -  Physics
KW  -  GRAPHITIC CARBON NITRIDE
KW  -  VISIBLE-LIGHT IRRADIATION
KW  -  HYDROGEN-PRODUCTION
KW  -  CHARGE SEPARATION
KW  -  NI CATALYST
KW  -  WATER
KW  -  SEMICONDUCTOR
KW  -  EVOLUTION
KW  -  PHOTOCATALYST
KW  -  COMPLEX
N2  - Graphitic carbon nitride (g-C3N4) synthesised from a urea precursor is an excellent CO2 reduction photocatalyst using [Co(bpy)n]2+ as a co-catalyst. A five-fold increase in activity for the highly polymerised urea derived g-C3N4 is achieved compared to alternative precursors. Transient absorption, time-resolved and steady-state emission studies indicate that the enhanced activity is related to both an increased driving force for photoelectron transfer and a greater availability of photogenerated charges.
ID  - discovery1522234
PB  - ROYAL SOC CHEMISTRY
TI  - Photochemical CO2 reduction using structurally controlled g-C3N4
AV  - public
Y1  - 2016/09/28/
EP  - 24829
JF  - Physical Chemistry Chemical Physics
A1  - Walsh, JJ
A1  - Jiang, C
A1  - Tang, J
A1  - Cowan, AJ
UR  - http://doi.org/10.1039/c6cp04525a
SN  - 1463-9076
IS  - 36
N1  - © Royal Society of Chemistry 2016
VL  - 18
SP  - 24825
ER  -