TY  - JOUR
A1  - Kuttatheyil, AV
A1  - Laessig, D
A1  - Lincke, J
A1  - Kobalz, M
A1  - Baias, M
A1  - Koenig, K
A1  - Hofmann, J
A1  - Krautscheid, H
A1  - Pickard, CJ
A1  - Haase, J
A1  - Bertmer, M
JF  - Inorganic Chemistry
SP  - 4431 
N1  - This document is the Accepted Manuscript version of a Published Work that appeared in final form in
Inorganic Chemistry, © 2013 American Chemical Society, after peer review and technical editing by the publisher.
To access the final edited and published work see http://dx.doi.org/10.1021/ic302643w
VL  - 52
EP  -  4442
UR  - http://dx.doi.org/10.1021/ic302643w
ID  - discovery1396211
IS  - 8
N2  - Synthesis and solid-state NMR characterization of two isomorphous series of zinc and cobalt coordination networks with 1,2,4-triazolyl benzoate ligands are reported. Both series consist of 3D diamondoid networks with four-fold interpenetration. Solid-state NMR identifies the metal coordination of the ligands, and assignment of all 1H and 13C shifts was enabled by the combination of 13C editing, FSLG-HETCOR spectra, and 2D 1H?1H back-to-back (BABA) spectra with results from NMR-CASTEP calculations. The incorporation of Co2+ replacing Zn2+ ions in the MOF over the full range of concentrations has significant influences on the NMR spectra. A uniform distribution of metal ions is documented based on the analysis of 1H T1 relaxation time measurements.
AV  - public
TI  - Synthesis, Crystal Structure, and Solid-State NMR Investigations of Heteronuclear Zn/Co Coordination Networks - A Comparative Study
SN  - 0020-1669
Y1  - 2013/04/15/
ER  -