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<https://discovery.ucl.ac.uk/id/eprint/1309819> <http://purl.org/dc/terms/title> "Radical hydroacylation of C-C and N-N double bonds in air"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/eprint/1309819> <http://purl.org/ontology/bibo/abstract> "The formation of C-C and C-N bonds in modern organic synthesis is a key target for\r\nmethodological advancement. Current methods of C-C and C-N bond formation\r\noften involve the use of expensive catalysts, or sub-stoichiometric reagents, which\r\ncan lead to the generation of undesirable waste products. This thesis describes a\r\nnovel and environmentally benign set of reaction conditions for the formation of C-C\r\nand C-N bonds by hydroacylation and this is promoted by mixing two reagents, an\r\naldehyde and an electron-deficient double bond, under freely available atmospheric\r\noxygen at room temperature\r\nChapter 1 will provide an introduction to the thesis and mainly discusses methods for\r\nC-C bond formation, in particular, radical chemistry and hydroacylation. Chapter 2\r\ndescribes the hydroacylation of vinyl sulfonates and vinyl sulfones (C-C double\r\nbonds) with aliphatic and aromatic aldehydes with a discussion and evidence for the\r\nmechanism of the transformation. Chapter 3 details the synthesis of precursors for\r\nintramolecular cyclisations and studies into aerobic intramolecular cyclisations.\r\nChapter 4 describes the hydroacylation of vinyl phosphonates (C-C double bonds)\r\nand diazocarboxylates (N-N double bonds) with aliphatic and aromatic aldehydes\r\nbearing functional groups. In addition, the hydroacylation of diazocarboxylates with\r\nchiral aldehydes will be discussed.\r\nIn conclusion, a new, facile and clean set of reaction conditions for the formation of\r\nC-C and C-N bonds has been developed via aerobic C-H activation of aldehydes\r\nproviding access to unsymmetrical ketones."^^<http://www.w3.org/2001/XMLSchema#string> .
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