eprintid: 123696 rev_number: 41 eprint_status: archive userid: 608 dir: disk0/00/12/36/96 datestamp: 2010-10-23 16:55:53 lastmod: 2021-12-13 01:51:39 status_changed: 2010-10-23 16:55:53 type: article metadata_visibility: show item_issues_count: 0 creators_name: Ramo, DM creators_name: Shluger, AL creators_name: Gavartin, JL creators_name: Bersuker, G title: Theoretical prediction of intrinsic self-trapping of electrons and holes in monoclinic HfO2 ispublished: pub divisions: UCL divisions: B04 divisions: C06 divisions: F60 keywords: STABILIZED ZIRCONIA, OXIDE, CRYSTALS, POLARONS, ENERGY, MODEL note: © 2007 The American Physical Society abstract: We predict, by means of ab initio calculations, stable electron and hole polaron states in perfect monoclinic HfO2. Hole polarons are localized on oxygen atoms in the two oxygen sublattices. An electron polaron is localized on hafnium atoms. Small barriers for polaron hopping suggest relatively high mobility of trapped charges. The one-electron energy levels in the gap, optical transition energies and ESR g-tensor components are calculated. date: 2007-10-12 publisher: AMER PHYSICAL SOC official_url: http://dx.doi.org/10.1103/PhysRevLett.99.155504 vfaculties: VMPS oa_status: green language: eng primo: open primo_central: open_green article_type_text: Article verified: verified_batch elements_source: Web of Science elements_id: 151081 doi: 10.1103/PhysRevLett.99.155504 language_elements: EN lyricists_name: Munoz Ramo, David lyricists_name: Shluger, Alexander lyricists_id: DMUNO86 lyricists_id: ASHLU39 full_text_status: public publication: PHYS REV LETT volume: 99 number: 15 article_number: 155504 issn: 0031-9007 citation: Ramo, DM; Shluger, AL; Gavartin, JL; Bersuker, G; (2007) Theoretical prediction of intrinsic self-trapping of electrons and holes in monoclinic HfO2. PHYS REV LETT , 99 (15) , Article 155504. 10.1103/PhysRevLett.99.155504 <https://doi.org/10.1103/PhysRevLett.99.155504>. Green open access document_url: https://discovery.ucl.ac.uk/id/eprint/123696/1/123696.pdf