eprintid: 10204923
rev_number: 9
eprint_status: archive
userid: 699
dir: disk0/10/20/49/23
datestamp: 2025-02-19 11:20:09
lastmod: 2025-02-19 11:20:09
status_changed: 2025-02-19 11:20:09
type: article
metadata_visibility: show
sword_depositor: 699
creators_name: Chen, J
creators_name: Li, W
creators_name: Huang, W
creators_name: Chen, Q
creators_name: Ma, Y
creators_name: Zhang, M
creators_name: Li, Z
creators_name: Fu, J
creators_name: Ouyang, X
title: Feasibility study of using carbonated and ultrasound treated electric arc furnace slag as a nano-enhanced supplementary cementitious material
ispublished: pub
divisions: UCL
divisions: B04
divisions: F44
keywords: CO2 sequestration, Aragonite, Hydration, Microstructure, Mechanical properties
note: This version is the author accepted manuscript. For information on re-use, please refer to the publisher's terms and conditions.
abstract: As a primary by-product of the electric arc furnace (EAF) steelmaking process, the relatively low carbonation capacity of EAF slag limits its use as a carbon-sequestering construction material. To address this limitation, this study proposed a two-step chemical-physical modification approach. First, a gas-solid carbonation process was applied, where humidity, temperature, CO₂ concentration, and carbonation duration were adjusted to specifically promote the growth of aragonite whiskers. Next, the carbonated EAF slag underwent liquid-phase ultrasound treatment, and the resulting liquid-solid mixture was used to prepare cement paste. The effect of the two-step modification was evaluated by characterizing the physical properties, microstructural evolution, and phase transformation of the EAF slag. The study further elucidated the feasibility of using modified EAF slag as a supplementary cementitious material (SCM) by examining its nucleation morphology, hydration products, and impact on hydration kinetics. Ultrasound treatment uniformly dispersed the aragonite whiskers, which acted as nanomaterials to fill the pores in the cement paste. Additionally, the exposed silica-rich surface facilitated the nucleation of C-S-H during hydration. The refined pore structure of the hardened paste ultimately resulted in a 30–50 % improvement in compressive strength compared to the untreated group and a 10–20 % increase compared to the pure ordinary Portland cement group. This study offers a novel perspective on utilizing EAF slag as an environmentally beneficial SCM, uncovering its potential properties while addressing the objectives of the CCUS strategy.
date: 2025-03
date_type: published
publisher: Elsevier BV
official_url: https://doi.org/10.1016/j.cemconcomp.2025.105946
full_text_type: other
language: eng
verified: verified_manual
elements_id: 2360231
doi: 10.1016/j.cemconcomp.2025.105946
lyricists_name: Zhang, Mingzhong
lyricists_id: MZHAA72
actors_name: Zhang, Mingzhong
actors_id: MZHAA72
actors_role: owner
full_text_status: restricted
publication: Cement and Concrete Composites
volume: 157
article_number: 105946
citation:        Chen, J;    Li, W;    Huang, W;    Chen, Q;    Ma, Y;    Zhang, M;    Li, Z;         ... Ouyang, X; + view all <#>        Chen, J;  Li, W;  Huang, W;  Chen, Q;  Ma, Y;  Zhang, M;  Li, Z;  Fu, J;  Ouyang, X;   - view fewer <#>    (2025)    Feasibility study of using carbonated and ultrasound treated electric arc furnace slag as a nano-enhanced supplementary cementitious material.                   Cement and Concrete Composites , 157     , Article 105946.  10.1016/j.cemconcomp.2025.105946 <https://doi.org/10.1016/j.cemconcomp.2025.105946>.      
 
document_url: https://discovery.ucl.ac.uk/id/eprint/10204923/7/Zhang_Feasibility%20study%20of%20using%20carbonated%20and%20ultrasound%20treated%20electric%20arc%20furnace%20slag%20as%20a%20nano-enhanced%20supplementary%20cementitious%20material_AAM.pdf