eprintid: 10199023
rev_number: 8
eprint_status: archive
userid: 699
dir: disk0/10/19/90/23
datestamp: 2024-10-29 11:00:37
lastmod: 2024-10-29 11:00:37
status_changed: 2024-10-29 11:00:37
type: article
metadata_visibility: show
sword_depositor: 699
creators_name: Wang, Jingyan
creators_name: Hwang, Gi Byoung
creators_name: Knapp, Caroline E
creators_name: Wilson, Daniel WN
title: Reversible CO₂ insertion into the silicon–nitrogen σ-bond of an N-heterocyclic iminosilane
ispublished: inpress
divisions: UCL
divisions: B04
divisions: C06
divisions: F56
note: © The Author(s), 2024. This is an Open Access article distributed under the terms of the Creative Commons Attribution Licence (CC BY 4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. https://creativecommons.org/licenses/by/4.0/
abstract: The reversible insertion of carbon dioxide into the silicon–nitrogen bond of an N-heterocyclic iminosilane is reported. Solution-phase thermodynamic investigations indicate that this process is thermoneutral and reversible, whereas in the solid-phase CO₂ can be stored for extended periods and is only released upon heating to 133 °C.
date: 2024-10-17
date_type: published
publisher: Royal Society of Chemistry (RSC)
official_url: https://doi.org/10.1039/D4CC04798B
oa_status: green
full_text_type: pub
language: eng
primo: open
primo_central: open_green
verified: verified_manual
elements_id: 2330244
doi: 10.1039/D4CC04798B
medium: Print-Electronic
lyricists_name: Knapp, Caroline
lyricists_name: Wilson, Daniel
lyricists_id: CEKNA05
lyricists_id: DWILS16
actors_name: Wilson, Daniel
actors_id: DWILS16
actors_role: owner
full_text_status: public
publication: Chemical Communications
event_location: England
issn: 1359-7345
citation:        Wang, Jingyan;    Hwang, Gi Byoung;    Knapp, Caroline E;    Wilson, Daniel WN;      (2024)    Reversible CO₂ insertion into the silicon–nitrogen σ-bond of an N-heterocyclic iminosilane.                   Chemical Communications        10.1039/D4CC04798B <https://doi.org/10.1039/D4CC04798B>.    (In press).    Green open access   
 
document_url: https://discovery.ucl.ac.uk/id/eprint/10199023/1/CO2Pulbished.pdf