%0 Journal Article
%@ 1359-7345
%A Wang, Jingyan
%A Hwang, Gi Byoung
%A Knapp, Caroline E
%A Wilson, Daniel WN
%D 2024
%F discovery:10199023
%I Royal Society of Chemistry (RSC)
%J Chemical Communications
%T Reversible CO₂ insertion into the silicon–nitrogen σ-bond of an N-heterocyclic iminosilane
%U https://discovery.ucl.ac.uk/id/eprint/10199023/
%X The reversible insertion of carbon dioxide into the silicon–nitrogen bond of an N-heterocyclic iminosilane is reported. Solution-phase thermodynamic investigations indicate that this process is thermoneutral and reversible, whereas in the solid-phase CO₂ can be stored for extended periods and is only released upon heating to 133 °C.
%Z © The Author(s), 2024. This is an Open Access article distributed under the terms of the Creative Commons Attribution Licence (CC BY 4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. https://creativecommons.org/licenses/by/4.0/