<> <http://www.w3.org/2000/01/rdf-schema#comment> "The repository administrator has not yet configured an RDF license."^^<http://www.w3.org/2001/XMLSchema#string> .
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<https://discovery.ucl.ac.uk/id/eprint/10198894> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://purl.org/ontology/bibo/AcademicArticle> .
<https://discovery.ucl.ac.uk/id/eprint/10198894> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://purl.org/ontology/bibo/Article> .
<https://discovery.ucl.ac.uk/id/eprint/10198894> <http://purl.org/dc/terms/title> "Identification and determination of the urinary metabolite of iodotyrosine in vivo"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/eprint/10198894> <http://purl.org/ontology/bibo/abstract> "Background: Congenital hypothyroidism screening traditionally relies on detecting elevated thyroid-stimulating\r\nhormone levels, yet this approach may not detect a specific type of congenital hypothyroidism caused by\r\niodotyrosine dehalogenase-1 (Dehal1) deficiency. The deficiency of this enzyme prevents the deiodination of\r\nmono-iodotyrosine (MIT) and di-iodotyrosine (DIT) in the process of iodine recycling. This underscores the\r\npotential use of iodotyrosine or its metabolites as non-invasive urinary biomarkers for early diagnosis of\r\ncongenital hypothyroidism. However, the urinary metabolites of MIT/DIT have not yet been discovered. Thus,\r\nthis study aimed to identify the urinary metabolites of iodotyrosine in experimental models.\r\nMethod: Gas chromatography mass spectrometry was used to identify the urinary metabolites of iodotyrosine\r\nfollowing intraperitoneal injection of MIT in rats. An isotope dilution mass spectrometric assay was developed for\r\nassessment of identified metabolites. Urine samples from Dehal1 knockout mice were used to confirm the results.\r\nResults: We identified novel iodotyrosine metabolites, 3-iodo-4-hydroxyphenylacetic acid (IHPA), and 3,5-diiodo4-hydroxyphenylacetic acid (Di-IHPA) as the primary urinary metabolites of MIT and DIT respectively. The\r\nconcentrations of urinary IHPA and Di-IHPA were significantly higher in Dehal1 knockout mice.\r\nConclusion: Our findings suggest that IHPA is detected in larger quantities and may hold more clinical significance than previously identified biomarkers like MIT and DIT, making it a promising candidate for diagnosing\r\ncongenital hypothyroidism or other conditions associated with iodine recycling inhibition."^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/eprint/10198894> <http://purl.org/dc/terms/date> "2024-10" .
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<https://discovery.ucl.ac.uk/id/eprint/10198894> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10198894#authors> .
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<https://discovery.ucl.ac.uk/id/eprint/10198894> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-957582e47ac7687a99a75c82947a7eef> .
<https://discovery.ucl.ac.uk/id/eprint/10198894> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10198894#authors> .
<https://discovery.ucl.ac.uk/id/eprint/10198894#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_9> <https://discovery.ucl.ac.uk/id/person/ext-957582e47ac7687a99a75c82947a7eef> .
<https://discovery.ucl.ac.uk/id/eprint/10198894> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-d0403c00368c47f6390dc307f58b40ff> .
<https://discovery.ucl.ac.uk/id/eprint/10198894> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10198894#authors> .
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<https://discovery.ucl.ac.uk/id/person/ext-ea9968eae313231934a0471155a902df> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> .
<https://discovery.ucl.ac.uk/id/person/ext-ea9968eae313231934a0471155a902df> <http://xmlns.com/foaf/0.1/givenName> "Pouya"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-ea9968eae313231934a0471155a902df> <http://xmlns.com/foaf/0.1/familyName> "Alikhani"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-ea9968eae313231934a0471155a902df> <http://xmlns.com/foaf/0.1/name> "Pouya Alikhani"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-fe7325911680d224bfa1fbdb836f67bd> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> .
<https://discovery.ucl.ac.uk/id/person/ext-fe7325911680d224bfa1fbdb836f67bd> <http://xmlns.com/foaf/0.1/givenName> "Kevin P"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-fe7325911680d224bfa1fbdb836f67bd> <http://xmlns.com/foaf/0.1/familyName> "Moore"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-fe7325911680d224bfa1fbdb836f67bd> <http://xmlns.com/foaf/0.1/name> "Kevin P Moore"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-21791f4d08c95ceb503eb4621d30fd4e> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> .
<https://discovery.ucl.ac.uk/id/person/ext-21791f4d08c95ceb503eb4621d30fd4e> <http://xmlns.com/foaf/0.1/givenName> "Danae"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-21791f4d08c95ceb503eb4621d30fd4e> <http://xmlns.com/foaf/0.1/familyName> "Zonias"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-21791f4d08c95ceb503eb4621d30fd4e> <http://xmlns.com/foaf/0.1/name> "Danae Zonias"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-d0403c00368c47f6390dc307f58b40ff> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> .
<https://discovery.ucl.ac.uk/id/person/ext-d0403c00368c47f6390dc307f58b40ff> <http://xmlns.com/foaf/0.1/givenName> "Ali R"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-d0403c00368c47f6390dc307f58b40ff> <http://xmlns.com/foaf/0.1/familyName> "Mani"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-d0403c00368c47f6390dc307f58b40ff> <http://xmlns.com/foaf/0.1/name> "Ali R Mani"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-788ee43b3288478915937a4097b55c9a> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> .
<https://discovery.ucl.ac.uk/id/person/ext-788ee43b3288478915937a4097b55c9a> <http://xmlns.com/foaf/0.1/givenName> "Cindy Xinyu"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-788ee43b3288478915937a4097b55c9a> <http://xmlns.com/foaf/0.1/familyName> "Ji"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-788ee43b3288478915937a4097b55c9a> <http://xmlns.com/foaf/0.1/name> "Cindy Xinyu Ji"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-aeafd4ad0b74d6cef68ad57e3a0546d5> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> .
<https://discovery.ucl.ac.uk/id/person/ext-aeafd4ad0b74d6cef68ad57e3a0546d5> <http://xmlns.com/foaf/0.1/givenName> "Ranchu"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-aeafd4ad0b74d6cef68ad57e3a0546d5> <http://xmlns.com/foaf/0.1/familyName> "Cheng"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-aeafd4ad0b74d6cef68ad57e3a0546d5> <http://xmlns.com/foaf/0.1/name> "Ranchu Cheng"^^<http://www.w3.org/2001/XMLSchema#string> .
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<https://discovery.ucl.ac.uk/id/person/ext-950c917b7cfe9954314dcf67fbb87574> <http://xmlns.com/foaf/0.1/givenName> "Kawther"^^<http://www.w3.org/2001/XMLSchema#string> .
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<https://discovery.ucl.ac.uk/id/person/ext-950c917b7cfe9954314dcf67fbb87574> <http://xmlns.com/foaf/0.1/name> "Kawther Salim"^^<http://www.w3.org/2001/XMLSchema#string> .
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<https://discovery.ucl.ac.uk/id/person/ext-6d2a11148b684ebf81d097f29da8d3ac> <http://xmlns.com/foaf/0.1/givenName> "Nafisa"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-6d2a11148b684ebf81d097f29da8d3ac> <http://xmlns.com/foaf/0.1/familyName> "Djumaeva"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-6d2a11148b684ebf81d097f29da8d3ac> <http://xmlns.com/foaf/0.1/name> "Nafisa Djumaeva"^^<http://www.w3.org/2001/XMLSchema#string> .
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<https://discovery.ucl.ac.uk/id/person/ext-de443a8b30ab7329ed42aabb1e98c8c9> <http://xmlns.com/foaf/0.1/givenName> "Tope"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-de443a8b30ab7329ed42aabb1e98c8c9> <http://xmlns.com/foaf/0.1/familyName> "Oyelade"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-de443a8b30ab7329ed42aabb1e98c8c9> <http://xmlns.com/foaf/0.1/name> "Tope Oyelade"^^<http://www.w3.org/2001/XMLSchema#string> .
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<https://discovery.ucl.ac.uk/id/person/ext-957582e47ac7687a99a75c82947a7eef> <http://xmlns.com/foaf/0.1/givenName> "José C"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-957582e47ac7687a99a75c82947a7eef> <http://xmlns.com/foaf/0.1/familyName> "Moreno"^^<http://www.w3.org/2001/XMLSchema#string> .
<https://discovery.ucl.ac.uk/id/person/ext-957582e47ac7687a99a75c82947a7eef> <http://xmlns.com/foaf/0.1/name> "José C Moreno"^^<http://www.w3.org/2001/XMLSchema#string> .
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