<> <http://www.w3.org/2000/01/rdf-schema#comment> "The repository administrator has not yet configured an RDF license."^^<http://www.w3.org/2001/XMLSchema#string> . <> <http://xmlns.com/foaf/0.1/primaryTopic> <https://discovery.ucl.ac.uk/id/eprint/10194588> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://purl.org/ontology/bibo/AcademicArticle> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://purl.org/ontology/bibo/Article> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/dc/terms/title> "Between carbide and nitride MAX phases: sol–gel assisted synthesis and characterization of the carbonitride phase Crâ‚‚GaCâ‚â‚‹â‚“Nâ‚“"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/ontology/bibo/abstract> "MAX phases are almost exclusively known as carbides, while nitrides and carbonitrides form a significantly underrepresented\r\nsubgroup even though they have been shown to possess enhanced properties in comparison to their carbide counterparts.\r\nOne example is the nitride phase Cr2GaN which exhibits a spin density wave magnetic state below T = 170 K, while the\r\nmetallic carbide phase Cr2GaC follows the MAX phase-typical Pauli-paramagnetic behavior. To investigate the influence on\r\nthe materials/functional properties of mixing carbon and nitrogen on the X-site, this study aims to synthesize and\r\ncomprehensively characterize the hitherto unknown carbonitride phase Cr2GaC1-xNx and compare it to the parent phases.\r\nDue to the challenging synthesis of (carbo)nitrides in general, a sol-gel-assisted approach is applied which was recently\r\ndeveloped by our group. This process was further improved by using time-efficient microwave heating, leading to a highly\r\nphase pure product. STEM-EDX analyses reveal a C/N ratio of roughly 2:1. Temperature-dependent XRD measurements\r\nconfirm the literature-known magnetic phase transition of the parent nitride phase Cr2GaN, while the incorporation of\r\ncarbon suppresses the latter. Nonetheless, magnetic characterization of the phases reveals that the magnetic behavior can\r\nbe specifically influenced by changing the composition of the X-site, resulting in an increase of the susceptibility by increasing\r\nthe nitrogen amount. Overall, these findings further substantiate the big potential in nitrogen-containing MAX phases, which\r\nwill also serve as starting materials for future doping studies, i.e. on the M- and A-site, and as precursors for novel 2D\r\nMXenes."^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/dc/terms/date> "2024-04-18" . <https://discovery.ucl.ac.uk/id/document/1756106> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://purl.org/ontology/bibo/Document> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/ontology/bibo/volume> "12" . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/ontology/bibo/issue> "21" . <https://discovery.ucl.ac.uk/id/org/ext-dfd5bdb84f8f568d04e12bd26542b7cb> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Organization> . <https://discovery.ucl.ac.uk/id/org/ext-dfd5bdb84f8f568d04e12bd26542b7cb> <http://xmlns.com/foaf/0.1/name> "ROYAL SOC CHEMISTRY"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/dc/terms/publisher> <https://discovery.ucl.ac.uk/id/org/ext-dfd5bdb84f8f568d04e12bd26542b7cb> . <https://discovery.ucl.ac.uk/id/publication/ext-20507526> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://purl.org/ontology/bibo/Collection> . <https://discovery.ucl.ac.uk/id/publication/ext-20507526> <http://xmlns.com/foaf/0.1/name> "Journal of Materials Chemistry C"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/dc/terms/isPartOf> <https://discovery.ucl.ac.uk/id/publication/ext-20507526> . <https://discovery.ucl.ac.uk/id/publication/ext-20507526> <http://www.w3.org/2002/07/owl#sameAs> <urn:issn:20507526> . <https://discovery.ucl.ac.uk/id/publication/ext-20507526> <http://purl.org/ontology/bibo/issn> "20507526" . <https://discovery.ucl.ac.uk/id/eprint/10194588> 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<http://www.w3.org/1999/02/22-rdf-syntax-ns#_2> <https://discovery.ucl.ac.uk/id/person/ext-6617d3da1db387c1915cad0f8cd49cfd> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-01d9ae521d2e524349339e039d214c6f> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> . <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_3> <https://discovery.ucl.ac.uk/id/person/ext-01d9ae521d2e524349339e039d214c6f> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-20e621c8f5e14fc87f1a90d47ca8daa4> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> . <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_4> <https://discovery.ucl.ac.uk/id/person/ext-20e621c8f5e14fc87f1a90d47ca8daa4> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-c025c3ba921563ab7121cd774035df64> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> . <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_5> <https://discovery.ucl.ac.uk/id/person/ext-c025c3ba921563ab7121cd774035df64> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-b9fbc7cea5191046d66fa5bc05434716> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> . <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_6> <https://discovery.ucl.ac.uk/id/person/ext-b9fbc7cea5191046d66fa5bc05434716> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-4670ca27537bf4d75548acaab6e6af76> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> . <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_7> <https://discovery.ucl.ac.uk/id/person/ext-4670ca27537bf4d75548acaab6e6af76> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-a236f5b8b73a7fd464166fe5ab936fbd> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> . <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_8> <https://discovery.ucl.ac.uk/id/person/ext-a236f5b8b73a7fd464166fe5ab936fbd> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-e07d0b4454079c0197385fd79b2a91e0> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> . <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_9> <https://discovery.ucl.ac.uk/id/person/ext-e07d0b4454079c0197385fd79b2a91e0> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-7e033a5bb7ec63eb13ccd3720f19f58a> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> . <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_10> <https://discovery.ucl.ac.uk/id/person/ext-7e033a5bb7ec63eb13ccd3720f19f58a> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-ca63039c7aa54f68770960a15afb4029> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> . <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_11> <https://discovery.ucl.ac.uk/id/person/ext-ca63039c7aa54f68770960a15afb4029> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-f39c3cc1867e950138f74f48ebc03f44> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> . <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_12> <https://discovery.ucl.ac.uk/id/person/ext-f39c3cc1867e950138f74f48ebc03f44> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-114cfa0f6ce024567f00dff1dfa77aed> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> . <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_13> <https://discovery.ucl.ac.uk/id/person/ext-114cfa0f6ce024567f00dff1dfa77aed> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-3be06783ccc334870da11524c923f150> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> . <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_14> <https://discovery.ucl.ac.uk/id/person/ext-3be06783ccc334870da11524c923f150> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/dc/terms/creator> <https://discovery.ucl.ac.uk/id/person/ext-ee142817bcb8f53be990cb570ddae4a9> . <https://discovery.ucl.ac.uk/id/eprint/10194588> <http://purl.org/ontology/bibo/authorList> <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> . <https://discovery.ucl.ac.uk/id/eprint/10194588#authors> <http://www.w3.org/1999/02/22-rdf-syntax-ns#_15> <https://discovery.ucl.ac.uk/id/person/ext-ee142817bcb8f53be990cb570ddae4a9> . <https://discovery.ucl.ac.uk/id/person/ext-7e033a5bb7ec63eb13ccd3720f19f58a> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-7e033a5bb7ec63eb13ccd3720f19f58a> <http://xmlns.com/foaf/0.1/givenName> "Wolfgang"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-7e033a5bb7ec63eb13ccd3720f19f58a> <http://xmlns.com/foaf/0.1/familyName> "Donner"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-7e033a5bb7ec63eb13ccd3720f19f58a> <http://xmlns.com/foaf/0.1/name> "Wolfgang Donner"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-ca63039c7aa54f68770960a15afb4029> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-ca63039c7aa54f68770960a15afb4029> <http://xmlns.com/foaf/0.1/givenName> "Hongbin"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-ca63039c7aa54f68770960a15afb4029> <http://xmlns.com/foaf/0.1/familyName> "Zhang"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-ca63039c7aa54f68770960a15afb4029> <http://xmlns.com/foaf/0.1/name> "Hongbin Zhang"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-6617d3da1db387c1915cad0f8cd49cfd> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-6617d3da1db387c1915cad0f8cd49cfd> <http://xmlns.com/foaf/0.1/givenName> "Isabel"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-6617d3da1db387c1915cad0f8cd49cfd> <http://xmlns.com/foaf/0.1/familyName> "Huck"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-6617d3da1db387c1915cad0f8cd49cfd> <http://xmlns.com/foaf/0.1/name> "Isabel Huck"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-b9fbc7cea5191046d66fa5bc05434716> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-b9fbc7cea5191046d66fa5bc05434716> <http://xmlns.com/foaf/0.1/givenName> "Bo"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-b9fbc7cea5191046d66fa5bc05434716> <http://xmlns.com/foaf/0.1/familyName> "Zhao"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-b9fbc7cea5191046d66fa5bc05434716> <http://xmlns.com/foaf/0.1/name> "Bo Zhao"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-a236f5b8b73a7fd464166fe5ab936fbd> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-a236f5b8b73a7fd464166fe5ab936fbd> <http://xmlns.com/foaf/0.1/givenName> "Tien-Lin"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-a236f5b8b73a7fd464166fe5ab936fbd> <http://xmlns.com/foaf/0.1/familyName> "Lee"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-a236f5b8b73a7fd464166fe5ab936fbd> <http://xmlns.com/foaf/0.1/name> "Tien-Lin Lee"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-01d9ae521d2e524349339e039d214c6f> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-01d9ae521d2e524349339e039d214c6f> <http://xmlns.com/foaf/0.1/givenName> "Hanna"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-01d9ae521d2e524349339e039d214c6f> <http://xmlns.com/foaf/0.1/familyName> "Pazniak"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-01d9ae521d2e524349339e039d214c6f> <http://xmlns.com/foaf/0.1/name> "Hanna Pazniak"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-ee142817bcb8f53be990cb570ddae4a9> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-ee142817bcb8f53be990cb570ddae4a9> <http://xmlns.com/foaf/0.1/givenName> "Christina S"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-ee142817bcb8f53be990cb570ddae4a9> <http://xmlns.com/foaf/0.1/familyName> "Birkel"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-ee142817bcb8f53be990cb570ddae4a9> <http://xmlns.com/foaf/0.1/name> "Christina S Birkel"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-3be06783ccc334870da11524c923f150> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-3be06783ccc334870da11524c923f150> <http://xmlns.com/foaf/0.1/givenName> "Anna"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-3be06783ccc334870da11524c923f150> <http://xmlns.com/foaf/0.1/familyName> "Regoutz"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-3be06783ccc334870da11524c923f150> <http://xmlns.com/foaf/0.1/name> "Anna Regoutz"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-fffb4e5a59151cba7992fafcfbaf0856> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-fffb4e5a59151cba7992fafcfbaf0856> <http://xmlns.com/foaf/0.1/givenName> "Niels"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-fffb4e5a59151cba7992fafcfbaf0856> <http://xmlns.com/foaf/0.1/familyName> "Kubitza"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-fffb4e5a59151cba7992fafcfbaf0856> <http://xmlns.com/foaf/0.1/name> "Niels Kubitza"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-20e621c8f5e14fc87f1a90d47ca8daa4> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> 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