eprintid: 10192299
rev_number: 7
eprint_status: archive
userid: 699
dir: disk0/10/19/22/99
datestamp: 2024-05-13 14:08:51
lastmod: 2024-05-13 14:08:51
status_changed: 2024-05-13 14:08:51
type: article
metadata_visibility: show
sword_depositor: 699
creators_name: Ramzan, Iqra
creators_name: Borowiec, Joanna
creators_name: Parkin, Ivan
creators_name: Carmalt, Claire J
title: Transparent Conductive Titanium and Fluorine Co-doped Zinc Oxide Films
ispublished: pub
divisions: UCL
divisions: B04
divisions: C06
divisions: F56
keywords: Transparent conducting oxides, Co-doped Zinc
oxide, Titanium and Fluorine co-doped Zinc oxide, electronic
materials, wide band gap mater
note: © 2024 The Authors. ChemPlusChem published by Wiley-VCH GmbH

This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
abstract: Aerosol-assisted chemical vapor deposition (AACVD) was used to deposit highly transparent and conductive titanium or fluorine-doped and titanium-fluorine co-doped ZnO thin films on glass substrate at 450 oC. All films were characterized by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), UV-Vis spectroscopy, scanning electron spectroscopy (SEM), and four-point probe. The films were 600-680 nm thick, crystalline, and highly transparent (80-87%). The co-doped film consisted of 0.70 at.% titanium and 1 at.% fluorine, and displayed a charger carrier mobility, charge carrier concentration, and a minimum resistivity of 8.4 cm2 V-1 s-1, 3.97 x 1020 cm-3, and 1.69 x 10-3 Ω cm, respectively. A band gap of 3.6 eV was observed for the co-doped film. Compared to the undoped and singly doped films, the co-doped film displayed a notably higher structure morphology (more homogenous grains with well-defined boundaries) suitable for transparent conducting oxide applications.
date: 2024-04-09
date_type: published
publisher: Wiley
official_url: https://doi.org/10.1002/cplu.202400073
oa_status: green
full_text_type: pub
language: eng
primo: open
primo_central: open_green
verified: verified_manual
elements_id: 2269369
doi: 10.1002/cplu.202400073
medium: Print-Electronic
lyricists_name: Carmalt, Claire
lyricists_id: CJCAR00
actors_name: Carmalt, Claire
actors_name: Zahnhausen-Stuber, Petra
actors_id: CJCAR00
actors_id: PMZAH20
actors_role: owner
actors_role: impersonator
full_text_status: public
publication: Chempluschem
article_number: e202400073
event_location: Germany
issn: 2192-6506
citation:        Ramzan, Iqra;    Borowiec, Joanna;    Parkin, Ivan;    Carmalt, Claire J;      (2024)    Transparent Conductive Titanium and Fluorine Co-doped Zinc Oxide Films.                   Chempluschem      , Article e202400073.  10.1002/cplu.202400073 <https://doi.org/10.1002/cplu.202400073>.       Green open access   
 
document_url: https://discovery.ucl.ac.uk/id/eprint/10192299/1/Carmalt_ChemPlusChem%20-%202024%20-%20Ramzan%20-%20Transparent%20Conductive%20Titanium%20and%20Fluorine%20Co%20doped%20Zinc%20Oxide%20Films.pdf