<> <http://www.w3.org/2000/01/rdf-schema#comment> "The repository administrator has not yet configured an RDF license."^^<http://www.w3.org/2001/XMLSchema#string> . <> <http://xmlns.com/foaf/0.1/primaryTopic> <https://discovery.ucl.ac.uk/id/eprint/10189560> . <https://discovery.ucl.ac.uk/id/eprint/10189560> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://purl.org/ontology/bibo/AcademicArticle> . <https://discovery.ucl.ac.uk/id/eprint/10189560> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://purl.org/ontology/bibo/Article> . <https://discovery.ucl.ac.uk/id/eprint/10189560> <http://purl.org/dc/terms/title> "Investigating the diastereoselective synthesis of a macrocycle under Curtin–Hammett control"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/eprint/10189560> <http://purl.org/ontology/bibo/abstract> "This work sheds new light on the stereoselective synthesis of chiral macrocycles containing twisted aromatic units, valuable π-conjugated materials for recognition, sensing, and optoelectronics. For the first time, we use the Curtin–Hammett principle to investigate a chiral macrocyclisation reaction, revealing the potential for supramolecular π–π interactions to direct the outcome of a dynamic kinetic resolution, favouring the opposite macrocyclic product to that expected under reversible, thermodynamically controlled conditions. Specifically, a dynamic, racemic perylene diimide dye (1 : 1 P : M) is strapped with an enantiopure (S)-1,1′-bi-2-naphthol group (P-BINOL) to form two diastereomeric macrocyclic products, the homochiral macrocycle (PP) and the heterochiral species (PM). We find there is notable selectivity for the PM macrocycle (dr = 4 : 1), which is rationalised by kinetic templation from intramolecular aromatic non-covalent interactions between the P-BINOL π-donor and the M-PDI π-acceptor during the macrocyclisation reaction."^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/eprint/10189560> <http://purl.org/dc/terms/date> "2024-03-05" . <https://discovery.ucl.ac.uk/id/document/1717409> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://purl.org/ontology/bibo/Document> . <https://discovery.ucl.ac.uk/id/org/ext-af3f8938911d08207333c9dcbe363a6c> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Organization> . <https://discovery.ucl.ac.uk/id/org/ext-af3f8938911d08207333c9dcbe363a6c> <http://xmlns.com/foaf/0.1/name> "Royal Society of Chemistry (RSC)"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/eprint/10189560> <http://purl.org/dc/terms/publisher> 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<http://xmlns.com/foaf/0.1/name> "Angus Yeung"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-d6806a9b5eeb810f83a058387964244d> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-d6806a9b5eeb810f83a058387964244d> <http://xmlns.com/foaf/0.1/givenName> "Martijn A"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-d6806a9b5eeb810f83a058387964244d> <http://xmlns.com/foaf/0.1/familyName> "Zwijnenburg"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-d6806a9b5eeb810f83a058387964244d> <http://xmlns.com/foaf/0.1/name> "Martijn A Zwijnenburg"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-7bbd48dc03508fba08b978926ac1c48b> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-7bbd48dc03508fba08b978926ac1c48b> <http://xmlns.com/foaf/0.1/givenName> "Jennifer H"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-7bbd48dc03508fba08b978926ac1c48b> <http://xmlns.com/foaf/0.1/familyName> "Robertson"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-7bbd48dc03508fba08b978926ac1c48b> <http://xmlns.com/foaf/0.1/name> "Jennifer H Robertson"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-a4d6adc6bf3996c8222a3a3c0e5488df> <http://www.w3.org/1999/02/22-rdf-syntax-ns#type> <http://xmlns.com/foaf/0.1/Person> . <https://discovery.ucl.ac.uk/id/person/ext-a4d6adc6bf3996c8222a3a3c0e5488df> <http://xmlns.com/foaf/0.1/givenName> "Timothy A"^^<http://www.w3.org/2001/XMLSchema#string> . <https://discovery.ucl.ac.uk/id/person/ext-a4d6adc6bf3996c8222a3a3c0e5488df> <http://xmlns.com/foaf/0.1/familyName> 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