%J Proceedings of the European Combustion Meeting %A Frederique Battin-Leclerc %A Frederic Buda %A Michael Fairweather %A Pierre-Alexandre Glaude %A John Griffiths %A Kevin Hughes %A Richard Porter %A Alison Tomlin %T The Effect of Formal Mechanism Reduction on Simulated Propane Autoignition and a Quantitative Assessment of the Impact of Uncertainties in Parameter Values %X Numerical simulations of a comprehensive propane/oxygen model are used to demonstrate the ranges of behaviour such as oscillatory cool flames and multiple stage ignitions found in a closed vessel. The model is evaluated by a construction of the closed vessel pressure – ambient temperature (p-Ta) ignition diagram and comparing it with experimental results. The model is then formally reduced using the techniques of sensitivity, rate of production and principal component analyses. A reduced chemical mechanism is produced which retains the main types of dynamic behaviour exhibited by the full model as well as their position within the p-Ta diagram. Global uncertainty analysis methods are used to establish the main contributors to uncertainties in output predictions. Results from application of a Monte Carlo uncertainty analysis are reported here. %L discovery10183584 %I European Combustion Meeting (ECM) %C Louvain la Neuve, Belgium %B Proceedings of the European Combustion Meeting 2005 %D 2005 %O This version is the version of record. For information on re-use, please refer to the publisher’s terms and conditions.