TY  - JOUR
UR  - https://doi.org/10.1021/acs.oprd.0c00162
Y1  - 2020/10/16/
N2  - A range of diazonium salts and their corresponding triazenes have been prepared in order to directly compare their relative thermal stabilities (via initial decomposition temperature) from differential scanning calorimetry (DSC) data. A structure?stability relationship has been explored to investigate trends in stability, depending on the aromatic substituent and the structure of the secondary amine component of the diazonium salts and triazenes. All of the triazenes investigated show significantly greater stability (many are stable above 200 °C) compared with the corresponding diazonium salts, which show varying stabilities.
TI  - Comparison of the Thermal Stabilities of Diazonium Salts and Their Corresponding Triazenes
JF  - Organic Process Research and Development
N1  - This version is the author accepted manuscript. For information on re-use, please refer to the publisher?s terms and conditions.
VL  - 24
ID  - discovery10098662
AV  - public
A1  - Schotten, C
A1  - Leprevost, SK
A1  - Yong, LM
A1  - Hughes, CE
A1  - Harris, KDM
A1  - Browne, DL
SP  - 2336
EP  - 2341
IS  - 10
KW  - triazene
KW  -  diazonium salt
KW  -  thermal stability
KW  -  DSC
KW  -  continuous processing
ER  -