%P 1959-1970 %O This version is the version of record. For information on re-use, please refer to the publisher’s terms and conditions. %D 2006 %V 368 %N 4 %L discovery10095566 %I WILEY-BLACKWELL %X We present high-quality optical spectroscopic observations of the planetary nebula (PN) Hf 2-2. The spectrum exhibits many prominent optical recombination lines (ORLs) from heavy-element ions. Analysis of the H I and He I recombination spectrum yields an electron temperature of ∼900 K, a factor of 10 lower than given by the collisionally excited [O III] forbidden lines. The ionic abundances of heavy elements relative to hydrogen derived from ORLs are about a factor of 70 higher than those deduced from collisionally excited lines (CELs) from the same ions, the largest abundance discrepancy factor (adf) ever measured for a PN. By comparing the observed O IIλ4089/λ4649 ORL ratio to theoretical value as a function of electron temperature, we show that the O II ORLs arise from ionized regions with an electron temperature of only ∼630 K. The current observations thus provide the strongest evidence that the nebula contains another previously unknown component of cold, high-metallicity gas, which is too cool to excite any significant optical or ultraviolet CELs and is thus invisible via such lines. The existence of such a plasma component in PNe provides a natural solution to the long-standing dichotomy between nebular plasma diagnostics and abundance determinations using CELs on the one hand and ORLs on the other. %K ISM: abundances, planetary nebulae: individual: Hf 2-2 %J Monthly Notices of the Royal Astronomical Society %T Chemical abundances for Hf 2-2, a planetary nebula with the strongest-known heavy-element recombination lines %A X-W Liu %A MJ Barlow %A Y Zhang %A RJ Bastin %A PJ Storey